Monocrotophos O,O-二甲基-2-甲基氨基甲酰基-1-甲基乙烯基磷酸酯
CAS 6923-22-4 MFCD00055291
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- Agro-Products
- Heterocycles
- Pharmaceuticals
- Intermediates & Fine Chemicals
- {uni_hamburg} no charge; amide; 1fragment
- {SA} Acaricides, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, H-M, Insecticides, M, METI - MZ, Method Specific, Oeko-Tex Standard 100, Organophorous, Pesticides, Pesticides & Metabolites
- {SNA} Acaricides, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Insecticides, M,
产品应用
- 速效广谱杀虫剂,主要用于各种作物上防治螨类、食吸甲虫、棉铃虫等。
相关文献及参考
- Short: EINECS
- Short: IV/8A
- Patel, I. et al.: Ind. J. Agric. Sci., 67, 83 (1997); Rao, V.L. et al.: Ind. J. Agric. Sci., 54, 209 (1984); Kinzer, R.E. et al.: J, Econ. Entomol., 69, 697 (1976);
- Merck: 14,6251
安全信息
GHS Symbol
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P273 Avoid release to the environment. 避免释放到环境中。
- P301+P310
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- H330 Fatal if inhaled 吸入致命
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
- H311 Toxic in contact with skin 皮肤接触中毒
- H300 Fatal if swallowed 吞食致命
- H300+H330
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S1/2 None 上锁保管并避免儿童触及;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
- R24 Toxic in contact with skin 与皮肤接触有毒
- R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
- R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
- R50/53
- R38 Irritating to skin 刺激皮肤
- R36 Irritating to eyes 刺激眼睛
- R11 Highly flammable 非常易燃
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
{h
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 9200 ug/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB277-077
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Bird - chicken DOSE/DURATION : 3540 ug/kg TOXIC EFFECTS : Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 11,49,1967
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 20 mg/kg TOXIC EFFECTS : Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - hypermotility, diarrhea REFERENCE : BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 19,47,1978
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 63 mg/m3/4H TOXIC EFFECTS : Behavioral - tremor Behavioral - muscle contraction or spasticity Lungs, Thorax, or
{hazard
TYPE OF TEST : Sister chromatid exchange TEST SYSTEM : Human Lymphocyte DOSE/DURATION : 12500 ng/L REFERENCE : BECTA6 Bulletin of Environmental Contamination and T
TYPE OF TES
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Yeast - Saccharomyces cerevisiae DOSE/DURATION : 2 pph REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB84-138973
TYPE OF T
TYPE OF TEST : Sister chromatid exchange TEST SYSTEM : Rodent - rat Cells - not otherwise specified DOSE/DURATION : 25 mg/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 188,311,1987
TYPE OF TEST : Sperm Morphology ROUTE OF EXPOSURE : Intraperitoneal TEST SYSTEM : Rodent - mouse DOSE/DURATION : 12500 ug/kg REFERENCE : CYTOAN Cytologia. (Japan Pub. Trading Co. (USA), 1255 Howard St., San Francisco, CA 94103) V.1- 1929- Volume(issue)/page/year: 53,801,1988
TYPE OF TEST : Cytogenetic analysis ROUTE OF EXPOSURE : Oral TEST SYSTEM : Rodent - mouse DOSE/DURATION : 5 mg/kg REFERENCE : CYTOAN Cytologia. (Japan Pub. Trading Co. (USA), 1255 Howard St., San Francisco, CA 94103) V.1- 1929- Volume(issue)/page/year: 53,801,1988
TYPE OF TEST : Cytogenetic analysis ROUTE OF EXPOSURE : Intraperitoneal TEST SYSTEM : Bird - chicken DOSE/DURATION : 5 mg/kg REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 292,231
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 16800 ug/kg SEX/DURATION : female 14 day(s) pre-mating TOXIC EFFECTS : Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) REFERENCE : INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 26,126,1994
其他信息
- MOL 文件:6923-22-4.mol
- RTECS号:TC4375000
- 毒害物质数据:6923-22-4(Hazardous Substances Data)
- HazardClass:6.1(a)
- NIST化学物质信息:Monocrotophos(6923-22-4)
- PackingGroup:II
- 有机磷杀虫剂:久效磷 是一种高效内吸性有机磷杀虫剂,有顺、反两种异构体,工业品是这两种异构体的混合物,常温下为褐色半固体,中性及酸性条件下较稳定;碱性条件下易分解,不可与碱性物质混用;对日光较稳定;对铁和黄铜有腐蚀性;能与水混溶,可溶于乙醇、丙酮,稍溶于二甲苯和煤油,难溶于脂肪烃,具有很强的触杀和胃毒作用。杀虫谱广,速效性好,残留期长,对刺吸、咀嚼和蛀食性的多种害虫有效。能防治稻螟、稻纵卷叶虫、稻苞虫、稻螟蛉、稻叶蝉、稻飞虱、抗性蚜虫、红蜘蛛、棉铃虫、棉红铃虫等多种害虫。作用机制为抑制昆虫体内的乙酰胆碱酯酶。久效磷还有一定的杀卵作用,适用于防治棉花、水稻、大豆、森林等作物上的多种害虫。 毒性 久效磷对鸟类及其他野生动物高毒;对鱼毒性较低;对虾类毒性高;对蜜蜂毒性高;对人畜有剧毒,但经皮毒性(与皮肤接触的毒性)低,使用时仍须注意安全。一般使用下对作物安全,但在寒冷地区对某些品种的苹果、樱桃、扁桃、桃和高粱有轻微药害。
- EPA化学物质信息:Phosphoric acid, dimethyl (1E)-1-methyl-3-(methylamino)- 3-oxo-1-propenyl ester(6923-22-4)
- 有轻微的酯味,能与水混溶,可溶于丙酮、乙醇、二氯甲烷,稍溶于二甲苯、乙醚,不溶于石油醚、柴油和煤油。在碱性介质中易分解,故不能与碱性农药混用。
- 图谱信息:久效磷(6923-22-4)核磁图( 13 CNMR) 久效磷(6923-22-4)质谱(MS) 久效磷(6923-22-4)核磁图( 1 HNMR) 久效磷(6923-22-4)红外图谱(IR1)