(-)-Isopinocampheylborane Tmeda Complex (-)-N,N’-双(单异松蒎基硼烷)-N,N,N’,N’-四甲基乙二胺复合物

CAS 67826-92-0 MFCD00077801

化学结构图

67826-92-0
SMILES: B[C@H]1C[C@H]2C[C@@H]([C@@H]1C)C2(C)C.B[C@H]1C[C@H]2C[C@@H]([C@@H]1C)C2(C)C.CN(C)CCN(C)C

化学属性

Mol. FormulaC26H54B2N2
Mol. Weight416.35
Melting Point139-141 °C(lit.)

别名和识别编码

Chemical Name(-)-Isopinocampheylborane Tmeda Complex
Synonym (-)-N,N′-双(单异松蒎基硼烷)-N,N,N′,N′-四甲基乙二胺 (R)-Alpine-Boramine™ (-)-异松蒎基硼烷-四甲基乙二胺络合物
MDL NumberMFCD00077801
PubChem Substance ID172089097
Chemical Name Translation(-)-N,N’-双(单异松蒎基硼烷)-N,N,N’,N’-四甲基乙二胺复合物
Reaxys-RN14457642
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Reduction

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H228 Flammable solid 易燃固体
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes F,Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
Risk Statements
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
Hazard Class4.1
UN Number 1325
Packing GroupII

系列性分类


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