CAS 6737-42-4 MFCD00003050-1,3-Bis(diphenylphosphino)propane 1,3-双(二苯基膦)丙烷 TAO{mole}

1,3-Bis(diphenylphosphino)propane 1,3-双(二苯基膦)丙烷

CAS 6737-42-4 MFCD00003050

化学结构图

SMILES: c1ccc(P(CCCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1

化学属性

Mol. Formula	C27H26P2
Mol. Weight	412.45
Density	1.422
Melting Point	58.0 to 63.0 deg-C
TSCA	Yes
Solubility	不溶
Flash Point	235°C
Appearance	white xtl.
Boiling Point	529.7°C at 760 mmHg
Redox	Reduction

别名和识别编码

Chemical Name	1,3-Bis(diphenylphosphino)propane
CAS Number	6737-42-4
Alfabeta Name	BISDIPHENYLPHOSPHINOPROPANE 13()-,
MDL Number	MFCD00003050
EC Number	229-791-2
Beilstein Registry Number	2821785
Synonym	1,3-Bis(diphenylphosphino)propane {LY} 1,3-Bis(diphenylphosphino)propane {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	81219
Reaxys-RN	2821785
Chemical Name Translation	1,3-双(二苯基膦)丙烷
LabNetwork Molecule ID	LN00155114
InChI	InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
Canonical SMILES	P(CCCP(C1=CC=CC=C1)C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4

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安全信息

Warnings IRRITANT

Signal word

GHS Symbol

WGK Germany3

Safety Statements

S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S37 Wear suitable gloves 戴适当手套；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P302+P352+P332+P313+P362+P364
P305+P351+P338+P337+P313

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from lig

Hazard Codes Xi

其他信息

Acros Organics:1,3-双二苯基磷丙烷(DPPP) 1,3-Bis(diphenylphosphino)propane, 97%(6737-42-4)
上游原料:乙醇 --> 氢氧化钠 --> 盐酸 --> 乙酸乙酯 --> 四氢呋喃 --> 二氯甲烷 --> 钠 --> 硫酸镁 --> 丙酮 --> 正丁基锂 --> 三苯基膦 --> 锂 --> 二苯基膦 --> 1,3-二溴丙烷 --> 1,3-二氯丙烷
海关编码:29310095
Sigma Aldrich:6737-42-4(sigmaaldrich)
敏感性:Air Sensitive
图谱信息:1,3-双(二苯基膦)丙烷(6737-42-4)红外图谱(IR1) 1,3-双(二苯基膦)丙烷(6737-42-4)质谱(MS)
MOL 文件:6737-42-4.mol
1,3-双(二苯基膦)丙烷价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B1138 1,3-双(二苯基膦基)丙烷 1,3-Bis(diphenylphosphino)propane 5G 230元 2014/06/02 B1138 1,3-双(二苯基膦基)丙烷 1,3-Bis(diphenylphosphino)propane 25G 790元 2010/06/21 310050050 1,3-双(二苯基膦)丙烷 1,3-Bis(diphenylphosphino)propane 97% 5 GR 696元
F:10-23
检测方法:HPLC
MSDS 信息:1,3-Bis(diphenylphosphino)propane(6737-42-4).msds
下游产品:1,3-双(二苯基膦丙烷)二氯化镍 --> 3-十二烷基噻吩
Alfa Aesar:1,3-二（二苯基膦）丙烷,97% 1,3-Bis(diphenylphosphino)propane, 97%(6737-42-4)
TCI Shanghai:1,3-双(二苯基膦基)丙烷 1,3-Bis(diphenylphosphino)propane,>;98.0%(GC)(T)(6737-42-4)