(S,S)-Chiraphos (2S,3S)-(-)-双(二苯基膦基)丁烷

CAS 64896-28-2 MFCD00009836

化学结构图

64896-28-2
SMILES: C[C@@H]([C@H](C)P(C1C=CC=CC=1)C1C=CC=CC=1)P(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC28H28P2
Mol. Weight426.48
Melting Point107.0 to 112.0 deg-C
TSCANo
Appearance white xtl.
Stabilityair sensitive

别名和识别编码

Chemical Name(S,S)-Chiraphos
Synonym (S,S)-Chiraphos (2S,3S)-(-)-2,3-双(二苯基膦)丁烷 (S,S)-手性膦 (2S,3S)-(-)-双(二苯膦)丁烷
MDL NumberMFCD00009836
PubChem Substance ID87558721
Beilstein Registry Number4268869
CAS Number64896-28-2
Chemical Name Translation(2S,3S)-(-)-双(二苯基膦基)丁烷
Reaxys-RN4268869
Merck Number2063
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Air Sensitive
Hazard Codes Xi

系列性分类


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