1,2,3,4-Tetrahydroquinoline 1,2,3,4-四氢喹啉
CAS 635-46-1 MFCD00006693
化学结构图
SMILES: c1ccc2c(c1)CCCN2
化学属性
| Mol. Formula | C9H11N |
|---|---|
| Mol. Weight | 133 |
| Refractive index | 1.5910 to 1.5960 |
| Boiling Point | 249 |
| Density | 1.061 |
| Melting Point | 9-14 |
| Flash Point | 113°C(lit.) |
| TSCA | Yes |
| Appearance | 浅黄色油状液体，密度 1.061,熔点 15-17℃ ,沸点 249℃,折射率 1.593-1.595,闪点 100 ℃,水溶性 <;1g/L (20℃) |
| Solubility | <1 g/L (20 °C) |
别名和识别编码
| Chemical Name | 1,2,3,4-Tetrahydroquinoline |
|---|---|
| CAS Number | 635-46-1 |
| Alfabeta Name | TETRAHYDROQUINOLINE 1234-,,, |
| MDL Number | MFCD00006693 |
| Synonym | 1,2,3,4-TETRAHYDROQUINOLINE 1,2,3,4-四硝基喹啉 1-AZATETRALIN Quinoline,1,2,3,4-tetrahydro- THQ |
| PubChem Substance ID | 69460 |
| Beilstein Registry Number | 20,262 |
| EC Number | 211-237-6 |
| Chemical Name Translation | 1,2,3,4-四氢喹啉 |
| Reaxys-RN | 116149 |
| LabNetwork Molecule ID | LN00173493 |
| InChI | InChI=1S/C9H11N/c1-2-6-9-8(4-1)5-3-7-10-9/h1-2,4,6,10H,3,5,7H2 |
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分类
- Building Blocks, C8 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Quinolines
- {SNA} Alphabetical Listings, Flavors and Fragrances, Q-Z
- {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Isoquinolines
相关文献及参考
- Beilstein:20,262
- 1,2,3,4-Tetrahydroquinoline derivatives are oxidized to N-hydroxy lactams by H2O2 in the presence of tungstate ion: J. Org. Chem., 55, 1744 (1990):
- 2-Metallation can be effected in a one-pot sequence via the Li carbamate: J. Chem. Soc., Perkin 1, 17 (1989); cf Indole, A14427.
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H350 May cause cancer 可能致癌
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P305+P351+P338+P337+P313
- P308+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37 Wear suitable gloves 戴适当手套；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R45 May cause cancer 可能致癌
其他信息
- 用途一:用于有机合成
- MOL 文件:635-46-1.mol
- TCI Shanghai:1,2,3,4-四氢喹啉 1,2,3,4-Tetrahydroquinoline,>;95.0%(GC)(635-46-1)
- 1,2,3,4-四氢喹啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010240 1,2,3,4-四氢喹啉 100g 360元 2011/04/16 T0113 1,2,3,4-四氢喹啉 1,2,3,4-Tetrahydroquinoline 25ML 208元 2011/04/16 T0113 1,2,3,4-四氢喹啉 1,2,3,4-Tetrahydroquinoline 500ML 1550元
- Alfa Aesar:1，2，3，4-四氢喹啉,99% 1,2,3,4-Tetrahydroquinoline, 99%(635-46-1)
- 水中溶解度: <1 g/L (20°C)， 溶于乙醇。
- 海关编码:29334990
- Acros Organics:1,2,3,4-四氢喹啉 1,2,3,4-Tetrahydroquinoline, 98%(635-46-1)
- 检测方法:GC,NMR
- MSDS 信息:1,2,3,4-Tetrahydroquinoline(635-46-1).msds
- Sigma Aldrich:635-46-1(sigmaaldrich)
- 图谱信息:1,2,3,4-四氢喹啉(635-46-1)质谱(MS) 1,2,3,4-四氢喹啉(635-46-1)核磁图( 13 CNMR) 1,2,3,4-四氢喹啉(635-46-1)核磁图( 1 HNMR) 1,2,3,4-四氢喹啉(635-46-1)红外图谱(IR1)
