CAS 624-18-0 MFCD00013002-p-Phenylenediamine dihydrochloride, 99% 1,4-苯二胺二盐酸盐 TAO{mole}

p-Phenylenediamine dihydrochloride, 99% 1,4-苯二胺二盐酸盐

CAS 624-18-0 MFCD00013002

化学结构图

SMILES: Cl.Cl.NC1CCC(N)CC1

化学属性

Mol. Formula	C6H8N2 . 2HCl
Mol. Weight
Density	1.15
Melting Point	No Data Available
TSCA	Yes
Solubility	>=10 G/100 ML AT 21 ºC
Appearance	白色至类白色粉状晶体，溶于醇水、氯仿等，性质比较稳定。
Stability	对光敏感
Boiling Point

别名和识别编码

Chemical Name	p-Phenylenediamine dihydrochloride, 99%
Synonym	P-Phenylenediamine Dihydrochloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} 1,4-Benzenediamine dihydrochloride
CAS Number	624-18-0
EC Number	210-834-9
Beilstein Registry Number	3911749
MDL Number	MFCD00013002
PubChem Substance ID	12205
Merck Number	7285
Reaxys-RN	3911749
Chemical Name Translation	1,4-苯二胺二盐酸盐
Wiswesser Line Notation	ZR DZ &GH 2
LabNetwork Molecule ID	LN00196572
InChI	InChI=1S/C6H8N2.2ClH/c7-5-1-2-6(8)4-3-5;;/h1-4H,7-8H2;2*1H

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安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Risk Statements

R50/53
R36 Irritating to eyes 刺激眼睛
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应

Precautionary statements

P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P301+P316
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P405 Store locked up. 上锁保管。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P403+P233
P337+P317
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P304+P340
P361+P364
P362+P364
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P305+P351+P338
P273 Avoid release to the environment. 避免释放到环境中。
P330 Rinse mouth. 漱口
P264+P265
P333+P317
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。

Hazard statements

H331 Toxic if inhaled 吸入中毒
H311 Toxic in contact with skin 皮肤接触中毒
H301 Toxic if swallowed 吞食有毒
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H319 Causes serious eye irritation 严重刺激眼睛
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H301+H311+H331

RTECSST0350000

Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Packing GroupIII

UN Number 1673

Hazard Codes 6.1

Hazard Class6.1

Warnings 危化品目录(2015)

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Amphibian - frog
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   XPHBAO U.S. Public Health Service, Public Health Bulletin.  (Washington, DC)
    Volume(issue)/page/year: 271,42,1941

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 147 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCILB* Progress Report for Contract No. NIH-NCI-E-C-72-3252, Submitted to
   the National Cancer Institute by Litton Bionetics, Inc.  (Bethesda, MD)
   Volume(issue)/page/year: NCI-E-C-72-3252,1973

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           :

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   XPHBAO U.S. Public Health Service, Public Health Bulletin.  (Washington, DC)
    Volume(issue)/page/year: 271,42,1941

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 20 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   XPHBAO U.S. Public Health Service, Public Health Bulletin.  (Washington, DC)
    Volume(issue)/page/year: 271,42,1941

TYPE OF TEST            : LD50 - Lethal dose, 50 percent

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 1250 ug/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   12(Suppl 13),103,1988

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 20 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 196,61,1988

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 341,161,1995

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7(Suppl
   5),1,1985

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 31300 ug/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   12(Suppl 13),103,1988

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 33300 ng/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For

Restrict 危险品

Storage condition +4°C 4 4℃

其他信息

Alfa Aesar:对苯二胺二盐酸盐,99% p-Phenylenediamine dihydrochloride, 99%(624-18-0)
Sigma Aldrich:624-18-0(sigmaaldrich)
可燃性危险特性:明火可燃; 受热放出有毒氯化氢和氧化氮气体
用途一:用作测定戊醇和硫化氢的试剂
类别:有毒物品
MSDS 信息:p-Phenylenediamine dihydrochloride(624-18-0).msds
Acros Organics:对苯二胺盐酸盐 p-Phenylenediamine dihydrochloride, 99+%(624-18-0)
对苯二胺盐酸盐价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80100314 盐酸对苯二胺 25g 7元 2011/04/16 P0152 1,4-苯二胺二盐酸盐 1,4-Phenylenediamine Dihydrochloride 500G 2160元 2011/04/16 P0152 1,4-苯二胺二盐酸盐 1,4-Phenylenediamine Dihydrochloride 25G 229元
海关编码:29215119
色指数:76061
MOL 文件:624-18-0.mol
储运特性:库房通风低温干燥; 与食品原料分开储运
用途三:主要用于日用化妆品的生产。
图谱信息:对苯二胺盐酸盐(624-18-0)红外图谱(IR2) 对苯二胺盐酸盐(624-18-0)红外图谱(IR1) 对苯二胺盐酸盐(624-18-0)核磁图( 1 HNMR) 对苯二胺盐酸盐(624-18-0)质谱(MS) 对苯二胺盐酸盐(624-18-0)核磁图( 13 CNMR)
溶于醇水、氯仿等，性质比较稳定。
F:8-9
下游产品:N,N,N',N'-四甲基对苯二胺二盐酸盐 --> 2,3,5-三甲基-2,5-环己二烯-1,4-二酮
TCI Shanghai:1,4-苯二胺二盐酸盐 1,4-Phenylenediamine Dihydrochloride,>;98.0%(LC)(T)(624-18-0)
用途二:用作染料中间体
毒性分级:高毒
急性毒性:口服-大鼠 LD50: 147 毫克/公斤; 腹腔-小鼠 LD50: 316 毫克/公斤
灭火剂:雾状水、二氧化碳、砂土、泡沫