D-Citramalic acid D-(-)-柠苹酸

CAS 6236-10-8 MFCD00066438

化学结构图

6236-10-8
SMILES: C[C@@](O)(CC(=O)O)C(=O)O

化学属性

Mol. FormulaC5H8O5· xLi+
Mol. Weight148.11 (free acid basis)
Melting Point108-110 °C(lit.)

别名和识别编码

Chemical NameD-(−)-Citramalic Acid Lithium Salt
Synonym (R)-2-Hydroxy-2-methylbutanedioic acid (R)-2-Hydroxy-2-methylsuccinic acid 2-Methylmalic acid D-(-)-2-Methylmalic acid (2R)-2-Hydroxy-2-methylsuccinic acid (-)-CITRAMALIC ACID (R)-(-)-CITRAMALIC ACID 2-甲蘋果酸 2-甲[基]蘋果酸 D-(-)-CITRAMALIC ACID (R)-(-)-Citramalic acid, 98+% (-)-2-METHYLMALIC ACID 2-HYDROXY-2-METHYLBUTANEDIOIC ACID (R)-2-HYDROXY-2-METHYLSUCCINIC ACID D-2-METHYLMALIC ACID (R)-(-)-柠苹酸 (-)-2-HYDROXY-2-METHYLBUTANEDIOIC ACID Α-羥-Α-甲基丁二酸 α-hydroxy-α-methyl-succinic acid Butanedioic acid, 2-hydroxy-2-methyl-, (2R)- (-)-2-Methyl-D-malic acid (R)-2-Hydroxy-2-methylbutanedioic acid, (R)-2-Hydroxy-2-methylsuccinic acid, 2-Methylmalic acid, D-(-)-2-Methylmalic acid (R)-2-羟基-2-甲基丁二酸 D-(-)-2-甲基苹果酸 檸蘋[果]酸 檸蘋酸 (R)-2-Hydroxy-2-methylsuccinic acid, D-(-)-2-Methylmalic acid (2R)-2-Methyl-2-hydroxybutanedioic acid (R)-(-)-2-HYDROXY-2-METHYLBUTANEDIOIC ACID D(-)-2-METHYLMALIC ACID D-(-)-柠苹酸 2-METHYLMALIC ACID
MDL NumberMFCD00066438
PubChem Substance ID439766
Beilstein Registry Number1723818
Chemical Name TranslationD-(-)-柠苹酸
CAS Number6236-10-8
Merck Number2323
InChIInChI=1S/C5H8O5/c1-5(10,4(8)9)2-3(6)7/h10H,2H2,1H3,(H,6,7)(H,8,9)/t5-/m1/s1
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分类

  • {SA} Asymmetric Synthesis, Carboxylic Acids, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Hazard Codes Xi
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

其他信息

  • F:3-10
  • MOL 文件:6236-10-8.mol
  • Sigma Aldrich:6236-10-8(sigmaaldrich)
  • TCI Shanghai:D-(-)-柠苹酸 D-(-)-Citramalic Acid,>;95.0%(GC)(6236-10-8)
  • (R)-(-)-柠苹酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/16 C1200 D-(-)-柠苹酸 D-(-)-Citramalic Acid 1G 1010元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Organic Acids - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Carboxylic Acids - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Functional Group 官能团索引
  2. alpha-hydroxyacid

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