1-Adamantyl Fluoroformate 氟甲酸金刚烷酯
CAS 62087-82-5 MFCD00074772
化学结构图
SMILES: O=C(F)O[C@@]12C[C@H]3C[C@@H](C1)C[C@@H](C2)C3 |&1:4,6,8,11|
化学属性
| Mol. Formula | C11H15FO2 |
|---|---|
| Mol. Weight | 198.23 |
| Melting Point | 30-32 °C(lit.) |
别名和识别编码
| Chemical Name | 1-Adamantyl Fluoroformate |
|---|---|
| CAS Number | 62087-82-5 |
| PubChem Substance ID | 24870779 |
| EC Number | 263-400-6 |
| Beilstein Registry Number | 3590131 |
| MDL Number | MFCD00074772 |
| Synonym | 1-金刚烷基氟甲酸 |
| Chemical Name Translation | 氟甲酸金刚烷酯 |
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分类
- {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
- Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
- {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Other Protecting and Derivatizing Reagents, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
相关文献及参考
- 1. L. Moroder et al. Hoppe Seyler's Z. Physiol. Chem. 357 , 1647, (1976) 摘要
- 2. G.W. Kenner et al. Tetrahedron 35 , 2767, (1979)
- 3. I.J. Galpin et al. Tetrahedron 35 , 2771, (1979)
- 4. R. Presentini, G. Antoni Int. J. Pept. Protein Res. 27 , 123, (1986)
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
