CAS 620-93-9 MFCD00059317-4,4-Dimethyldiphenylamine 4,4-二甲基二苯胺 TAO{mole}

4,4-Dimethyldiphenylamine 4,4-二甲基二苯胺

CAS 620-93-9 MFCD00059317

化学结构图

SMILES: Cc1ccc(Nc2ccc(C)cc2)cc1

化学属性

Mol. Formula	C14H15N
Mol. Weight	197.28
Melting Point	78-82°C
Boiling Point	330°C at 760 mmHg
Density	1.049

别名和识别编码

Chemical Name	4,4-Dimethyldiphenylamine
CAS Number	620-93-9
Alfabeta Name	DIMETHYLDIPHENYLAMINE 44-,'
MDL Number	MFCD00059317
Synonym	4,4'-Dimethyldiphenylamine {LY} 4,4'-Dimethyldiphenylamine {} {LY} 4,4'-Dimethyldiphenylamine {} {} {LY} 4,4'-Dimethyldiphenylamine {} {} {} {LY} 4,4'-Dimethyldiphenylamine {} {} {} {} {LY} 4,4'-Dimethyldiphenylamine {} {} {} {} {} {LY} 4,4'-Dimethyldiphenylamine {} {} {} {} {} {} {LY} 4,4'-Dimethyldiphenylamine {} {} {} {} {} {} {} {LY} 4,4'-Dimethyldiphenylamine {} {} {} {} {} {} {} {} {LY} 4,4'-Dimethyldiphenylamine {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dimethyldiphenylamine {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dimethyldiphenylamine {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dimethyldiphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dimethyldiphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dimethyldiphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dimethyldiphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	69293
EC Number	210-659-8
Beilstein Registry Number	2210252
Reaxys-RN	2210252
Chemical Name Translation	4,4-二甲基二苯胺
InChIKey	RHPVVNRNAHRJOQ-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00173979
InChI	InChI=1S/C14H15N/c1-11-3-7-13(8-4-11)15-14-9-5-12(2)6-10-14/h3-10,15H,1-2H3
Canonical SMILES	C1=CC(=CC=C1NC2=CC=C(C)C=C2)C

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安全信息

Warnings IRRITANT

WGK Germany3

Signal word

Hazard statements

H302 Harmful if swallowed 吞食有害
H302+H312+H332
H312 Harmful in contact with skin 皮肤接触有害
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H332 Harmful if inhaled 吸入有害
H335 May cause respiratory irritation 可能导致呼吸道刺激

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312
P301+P312+P330
P302+P350
P302+P352
P302+P352+P312+P362+P364
P304+P312
P304+P340
P305+P351+P338
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

GHS Symbol

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

图谱信息:4,4'-二甲基二苯胺(620-93-9)红外图谱(IR1) 4,4'-二甲基二苯胺(620-93-9)核磁图( 13 CNMR) 4,4'-二甲基二苯胺(620-93-9)核磁图( 1 HNMR) 4,4'-二甲基二苯胺(620-93-9)质谱(MS) 4,4'-二甲基二苯胺(620-93-9)红外图谱(IR2)
TCI Shanghai:二(4，4'-二甲苯基)胺 p,p'-Ditolylamine,>;97.0%(GC)(620-93-9)
合成与制备方法:第一种方法:由于芳卤化合物与芳伯胺反应不仅生成二芳胺，还生成三芳胺,所以对碘甲苯和对甲苯胺反应生成4,4'-二甲基二苯胺同时生成大量的4,4',4''-三甲基三苯胺。第二种方法:对甲苯胺酰化再与对碘甲苯反应，最后进行水解的方法制备4,4'-二甲基二苯胺。该反应弥补了芳卤化合物与芳伯胺直接反应的不足，收率虽然低,但不产生4,4',4''-三甲基三苯胺。
MOL 文件:620-93-9.mol
4,4'-二甲基二苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 D0950 p,p'-二甲苯基胺 p,p'-Ditolylamine 5G 984元 2014/06/02 D0950 p,p'-二甲苯基胺 p,p'-Ditolylamine 25G 2750元
MSDS 信息:Di-p-tolylamine(620-93-9).msds
Sigma Aldrich:620-93-9(sigmaaldrich)