Phenylmercury acetate 乙酸苯汞
CAS 62-38-4 MFCD00008691
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分类
- {SNA} Chemical Synthesis, Organomercury, Organometallic Reagents
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
- H301 Toxic if swallowed 吞食有毒
- P273 Avoid release to the environment. 避免释放到环境中。
- P301+P310
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
- S37 Wear suitable gloves 戴适当手套;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- R34 Causes burns 会导致灼伤
- R25 Toxic if swallowed 吞咽有毒
- R48/24/25
- R50/53
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 41 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,175,1992
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Unreported SPECIES OBSERVED : Mammal - species unspecified DOSE/DURATION : 17 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971 Volume(issue)/page/year: -,295,1971
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 18 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00921
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 13 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AMSVAZ Acta Medica Scandinavica. (Almqvist & Wiksell, POB 45150, S-10430 Stockholm, Sweden) V.52-224, 1919-88. Volume(issue)/page/year: 143,365,1952
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Subcutaneou
TYPE OF TEST : Sex chromosome loss and nondisjunction ROUTE OF EXPOSURE : Oral TEST SYSTEM : Insect - Drosophila melanogaster DOSE/DURATION : 200 ppm REFERENCE : ENVRAL Environmental Research. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1967- Volume(issue)/page/year: 36,218,1985
TYPE OF TEST : Siste
TYPE OF TEST : DNA repair TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 2 mmol/L REFERENCE : MJDHDW Mukogawa Joshi Daigaku Kiyo, Shokumotsu-hen. Bulletin of Mukogawa Women's University, Food Science Series. (Mukogawa Joshi Daigaku, 6-46, Ikebiraki-cho, Nishinomiya, Hyogo-ken, Japan) No.19- 1972- Volume(issue)/page/year: 28,F39,1980
TYPE OF TEST : DNA repair TEST SYSTEM : Bacteria - Bacillus subtilis DOSE/DURATION : 1 mmol/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 77,109,1980
TYPE OF TEST : DNA repair TEST SYSTEM : Bacteria - Bacillus subtilis DOSE/DURATION : 50 mmol/L REFERENCE : MUREAV
TYPE OF TEST : DNA inhibition TEST SYSTEM : Rodent - mouse Lymphocyte DOSE/DURATION : 1 umol/L REFERENCE : BCPCA6 Biochemical Pharmacology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.1- 1958- Volume(issue)/page/year: 24,489,1975
TYPE OF TEST : Mutation test systems - not otherwise specified TEST SYSTEM : Rodent - mouse Lymphocyte DOSE/DURATION : 10 umol/L REFERENCE : BCPCA6 Biochemical Pharmacology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.1- 1958- Volume(issue)/page/year: 24,489,1975
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - hamster DOSE : 7500 ug/kg SEX/DURATION : female 8 day(s) after conception TOXIC EFFECTS : Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Specific Developmental Abnormalities - homeostasis REFERENCE : LSBGAY Life Sciences, Part 2: Biochemistry, General and Molecular Biology. (New York, NY) V.9-13, 1970-73. For publisher information, see LIFSAK. Volume(issue)/page/year: 10,1341,1971
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intravaginal SPECIES OBSERVED : Rodent - mouse DOSE : 110 ug/kg SEX/DURATION : female 7 day(s) after conception TOXIC EFFECTS : Reproductive - Effects on Embryo or Fetus - fetal death Reproductive - Specific Developmental Abnormalities - musculoskeletal system REFERENCE : ARINAU Annual Report of the Research Institute of Environmental Medicine, Nagoya University. (Nagoya, Japan) V.1-25, 1951-80. Volume(issue)/page/year: 3,88,1956
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 15 mg/kg SEX/DURATION : female 6-10 day(s) after conception TOXIC EFFECTS : Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Specific Developmental Abnormalities - homeostasis Reproductive - Specific Developmental Abnormalities - other developmental abnormalities REFERENCE : PARWAC Polskie Archiwum Weterynaryjne. Polish Archives of Veterinary
其他信息
- 灭火剂:水、泡沫、砂土、二氧化碳
- 上游原料:氢氧化钠 --> 乙酸 --> 硝酸 --> 苯 --> 汞 --> 氧化汞(II), 黄
- 外观性质:白色有光泽斜方晶体。
- 图谱信息:苯基醋酸汞(62-38-4)红外图谱(IR1) 苯基醋酸汞(62-38-4)红外图谱(IR2) 苯基醋酸汞(62-38-4)Raman光谱 苯基醋酸汞(62-38-4)核磁图( 1 HNMR)
- 刺激数据:眼- 兔子 0.005 毫克/ 24小时 重度
- 急性毒性:口服- 大鼠 LD50: 41 毫克/ 公斤; 口服- 小鼠 LD50: 13.25 毫克/ 公斤
- 毒性分级:剧毒
- MSDS 信息:醋酸苯汞(62-38-4).msds
- Acros Organics:苯基醋酸汞 Phenylmercuricacetate,98%(62-38-4)
- TSCA:Yes
- MOL 文件:62-38-4.mol
- Sigma Aldrich:62-38-4(sigmaaldrich)
- 类别:农药
- 中毒症状:对皮肤、眼睛和呼吸道具有中度刺激作用,使皮肤产生过敏反应。
- 用途二:作为农药主要用于拌种,可防治稻瘟病、白叶枯病、菌核病等多种病害,但目前已不作农药使用。在医药工业中用作避孕药的一种原料。
- 用途一:用作医用杀菌剂、农用除莠剂、聚氨酯塑胶催化剂、防霉剂等
- 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
- 下游产品:J-686系列压敏胶粘剂 --> 硝酸苯汞
- F:8
- 职业标准:TLV-TWA 0.1 毫克 (汞)/ 立方米; STEL 0.15 毫克(汞)/ 立方米
- 急救治疗:(1)用肥皂和水清洗皮肤,用大量水冲洗眼睛。如果仍感觉有刺激作用,则应进行专门的治疗(2)如果几小时前大量吞服,但并未出现大量呕吐,则必须洗胃,并采取措施减少胃肠吸收 (3)如患者伴有血压下降症状时,须采取对症治疗,无特效解毒药。
- 苯基醋酸汞价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80100924 乙酸苯汞(剧毒) 25g 800元
- 注意事项:对实验动物急性吸入毒性高和慢性毒性问题已撤消登记
- 可燃性危险特性:遇明火、高热可燃; 受热产生有毒含汞化物烟雾
- Alfa Aesar:苯基乙酸汞,98% Phenylmercury acetate, 98%(62-38-4)
- 方法一:由苯、乙酸和氧化汞一步合成,经后处理制得。