CAS 618-40-6 MFCD00007627-1-Methyl-1-Phenylhydrazine 1-甲基-1-苯肼 TAO{mole}

1-Methyl-1-Phenylhydrazine 1-甲基-1-苯肼

CAS 618-40-6 MFCD00007627

化学结构图

SMILES: CN(N)c1ccccc1

化学属性

Mol. Formula	C7H10N2
Mol. Weight	122.17
Refractive index	1.5810 to 1.5850
Boiling Point	54-55 °C at 0.3 mmHg
Density	1.038 g/mL at 25 °C(lit.)
Flash Point	92°C(lit.)
TSCA	Yes
Solubility	微溶
Appearance	无色或浅黄色液体。沸点227℃（99.3kPa），131℃（4.67kPa），相对密度1.0404（20/4℃），折光率1.5691，闪点96℃。能与乙醇、乙醚、氯仿和苯混溶，微溶于水。

别名和识别编码

Chemical Name	1-Methyl-1-Phenylhydrazine
Synonym	1-Methyl-1-phenylhydrazine {LY} 1-Methyl-1-phenylhydrazine {} {LY} 1-Methyl-1-phenylhydrazine {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Methyl-1-phenylhydrazine
CAS Number	618-40-6
PubChem Substance ID	36299
EC Number	210-547-9
Beilstein Registry Number	15,117
MDL Number	MFCD00007627
Reaxys-RN	507683
Chemical Name Translation	1-甲基-1-苯肼
InChIKey	MWOODERJGVWYJE-UHFFFAOYSA-N
LabNetwork Molecule ID	LN01354733
InChI	InChI=1S/C7H10N2/c1-9(8)7-5-3-2-4-6-7/h2-6H,8H2,1H3
Canonical SMILES	NN(C)C1=CC=CC=C1

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H227 Combustible liquid 可燃液体
H302 Harmful if swallowed 吞食有害
H302+H312+H332
H312 Harmful in contact with skin 皮肤接触有害
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H332 Harmful if inhaled 吸入有害
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes Xn

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312
P301+P312+P330
P302+P350
P302+P352
P302+P352+P312+P362+P364
P304+P312
P304+P340
P305+P351+P338
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Warning

RTECSMV7712000

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R22 Harmful if swallowed 吞咽有害

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；

Packing GroupIII

Hazard Class6.1(b)

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

UN Number 2810

其他信息

用途一:用于有机合成，用于酮和糖的测定。
下游产品:2,3,4,5-四氢-5-甲基-1H-吡啶并[4,3-b]吲哚-1-酮 --> 5,6-二氢-4-(2-甲基-2-苯基肼基)-2-1H-吡啶酮
Sigma Aldrich:618-40-6(sigmaaldrich)
上游原料:锌粉 --> N-甲基苯胺
方法一:由N-亚硝基甲基苯胺还原而得。将锌粉和水搅成悬浮液，在10-20℃缓缓加入N-亚硝基甲基胺和冰醋酸配成的溶液，加毕，在室温下继续搅拌1h。然后加热到80℃，趁热滤出未反应的锌粉。滤液冷却后加入过量的40%氢氧化钠溶液，使沉淀出来的氢氧化钠重新溶解。分出油层，减压蒸馏，收集106-109℃（1.73kPa）馏分，即为成品。收率50%以上。
Alfa Aesar:1-甲基-1-苯肼,97% 1-Methyl-1-phenylhydrazine, 97%(618-40-6)
1-甲基-1-苯肼价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 M0399 1-甲基-1-苯肼 1-Methyl-1-phenylhydrazine 25G 1670元 2010/06/21 354790050 1-甲基-1-苯肼 1-Methyl-1-phenylhydrazine 96% 5 GR 1508元 2010/06/21 354790250 1-甲基-1-苯肼 1-Methyl-1-phenylhydrazine 96% 25 GR 4465元
MOL 文件:618-40-6.mol
F:8-10-23
Acros Organics:1-甲基-1-苯肼 1-Methyl-1-phenylhydrazine, 96%(618-40-6)
TCI Shanghai:1-甲基-1-苯肼 1-Methyl-1-phenylhydrazine,>;95.0%(GC)(618-40-6)
图谱信息:1-甲基-1-苯肼(618-40-6)红外图谱(IR2) 1-甲基-1-苯肼(618-40-6)核磁图( 13 CNMR) 1-甲基-1-苯肼(618-40-6)红外图谱(IR1) 1-甲基-1-苯肼(618-40-6)核磁图( 1 HNMR) 1-甲基-1-苯肼(618-40-6)质谱(MS)