CAS 6163-58-2 MFCD00008514-Tri(o-tolyl)phosphine 三(邻甲苯基)膦 TAO{mole}

Tri(o-tolyl)phosphine 三(邻甲苯基)膦

CAS 6163-58-2 MFCD00008514

化学结构图

SMILES: Cc1ccccc1P(c1ccccc1C)c1ccccc1C

化学属性

Mol. Formula	C21H21P
Mol. Weight	304.37
Density	1.589
Melting Point	123-125
TSCA	Yes
Boiling Point	412.4±44.0 °C at 760 mmHg
Appearance	白色晶体
Stability	air sensitive

别名和识别编码

Chemical Name	Tri(o-tolyl)phosphine
CAS Number	6163-58-2
Alfabeta Name	TRITOLYLPHOSPHINE M()-
MDL Number	MFCD00008514
Synonym	Tri(2-methylphenyl)phosphine {LY} Tri(2-methylphenyl)phosphine {} {LY} Tri(2-methylphenyl)phosphine {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {
EC Number	228-193-9
Beilstein Registry Number	661212
PubChem Substance ID	80271
Reaxys-RN	661212
Chemical Name Translation	三(邻甲苯基)膦
InChIKey	COIOYMYWGDAQPM-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00173237
InChI	InChI=1S/C21H21P/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3/h4-15H,1-3H3
Canonical SMILES	CC1=C(C=CC=C1)P(C(C=CC=C2)=C2C)C(C=CC=C3)=C3C

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

配体，用于钌催化的醇的氨基化反应。

安全信息

Warnings IRRITANT

Signal word Warning

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S37 Wear suitable gloves 戴适当手套；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P305+P351+P338+P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes Xi

Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

其他信息

下游产品:5-甲基吲哚
存储注意事项:光敏感
Sigma Aldrich:6163-58-2(sigmaaldrich)
上游原料:乙醇 --> 氢氧化钠 --> 盐酸 --> 乙酸乙酯 --> 乙醚 --> 四氢呋喃 --> 二氯甲烷 --> 石油醚 --> 硫酸钠 --> 氯化钠 --> 氯化铵 --> 镁 --> 三氯化磷 --> 碘 --> 1,2-二溴乙烷 --> 左旋酒石酸 --> 2-溴甲苯
Acros Organics:三(邻-甲苯基)磷 Tri-o-tolylphosphine, 99%(6163-58-2)
三(邻甲基苯基)磷价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 T1024 三(2-甲苯基)膦 Tris(2-methylphenyl)phosphine 25G 1320元 2014/06/02 T1024 三(2-甲苯基)膦 Tris(2-methylphenyl)phosphine 5G 484元 2010/06/21 422320010 三(邻甲基苯基)磷 Tri-o-tolylphosphine 99% 1 GR 328元
F:10-23
用途二:配体，用于钌催化的醇的氨基化反应。
MOL 文件:6163-58-2.mol
Alfa Aesar:三(邻甲苯)膦,98+% Tri(o-tolyl)phosphine, 98+%(6163-58-2)
检测方法:HPLC,NMR
TCI Shanghai:三(2-甲基苯基)膦 Tris(2-methylphenyl)phosphine,>;95.0%(GC)(6163-58-2)
用途一:作为配体，用于偶联反应中