1,1-Thiocarbonyldiimidazole 1,1-硫羰基二咪唑
CAS 6160-65-2 MFCD00005289
化学结构图
SMILES: S=C(n1ccnc1)n1ccnc1
化学属性
| Mol. Formula | C7H6N4S |
|---|---|
| Mol. Weight | 178.21 |
| Melting Point | 98-102°C |
| TSCA | No |
| Solubility | 分解 |
| Density | 1.39 |
| Stability | 对湿度敏感 |
| Boiling Point | 390.8°C at 760 mmHg |
别名和识别编码
| Chemical Name | 1,1-Thiocarbonyldiimidazole |
|---|---|
| CAS Number | 6160-65-2 |
| Alfabeta Name | THIOCARBONYLDIIMIDAZOLE 11-,' |
| MDL Number | MFCD00005289 |
| Synonym | Thiocarbonyldiimidazole {LY} Thiocarbonyldiimidazole {} {LY} Thiocarbonyldiimidazole {} {} {LY} Thiocarbonyldiimidazole {} {} {} {LY} Thiocarbonyldiimidazole {} {} {} {} {LY} Thiocarbonyldiimidazole {} {} {} {} {} {LY} Thiocarbonyldiimidazole {} {} {} {} {} {} {LY} Thiocarbonyldiimidazole {} {} {} {} {} {} {} {LY} Thiocarbonyldiimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiocarbonyldiimidazole {} {} {} {} {} {} {} {} {} {LY} Thiocarbonyldiimidazole {} {} {} {} {} {} {} {} {} {} {LY} Thiocarbonyldiimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiocarbonyldiimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiocarbonyldiimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiocarbonyldiimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiocarbonyldiimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiocarbony |
| EC Number | 228-183-4 |
| Beilstein Registry Number | 609349 |
| PubChem Substance ID | 87566387 |
| Chemical Name Translation | 1,1-硫羰基二咪唑 |
| Reaxys-RN | 609349 |
| InChIKey | RAFNCPHFRHZCPS-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00174471 |
| Canonical SMILES | S=C(N1C=CN=C1)N2C=CN=C2 |
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- Sulfur & Selenium Compounds
- Heterocycles
- Amines
- {SNA} Building Blocks, C3 to C8, Carbonyldiimidazole Derivatives, Chemical Synthesis, Coupling, Heterocyclic Building Blocks, Imidazoles, Synthetic Reagents
- {SNA} Carbonyldiimidazole Derivatives, Chemical Synthesis, Coupling, Synthetic Reagents
产品应用
- 合成硫代酰胺的试剂；从醇中制备硫代甲酸酯，期间要和Bu3SnH-AIBN3剧烈反应。
相关文献及参考
- Reacts with diols to give cyclic thionocarbonates which are desulfurized by trialkyl phosphites to give alkenes by cis-elimination of CO2 from the intermediate carbene (Corey-Winter olefination): J. Am. Chem. Soc., 85, 2677 (1963); Angew. Chem. Int. Ed., 14, 753 (1975). For a modified procedure involving ring-opening of the thionocarbonate intermediate with an alkyl iodide, followed by Zn reduction of the resulting iodo ester, see: Tetrahedron Lett., 3793 (1973). Alternatively, the thionocarbonate of a 1,2-diol can be selectively reduced to the methylenedioxy group with Triphenyltin hydride, L00163, under free-radical conditions: J. Org. Chem., 62, 4159 (1997).
- Can be used to deoxygenate carbocyclic monosaccharide analogues: Tetrahedron., 48, 2349 (1992).
- Loke, I., et al.: Tetrahedron, 68,?697 (2012),
安全信息
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S22 Do not breathe dust 不要吸入粉尘；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- H315 Causes skin irritation 会刺激皮肤
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P332+P313
- P305+P351+P338+P337+P313
- P302+P350
- P337+P313
- P301+P312
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P301+P330+P331
GHS Symbol
其他信息
- 溶于水并分解。
- Alfa Aesar:1,1'-硫代碳酰基二咪唑,tech.90% 1,1'-Thiocarbonyldiimidazole, tech 90%(6160-65-2)
- F:9-21
- 敏感性:Moisture Sensitive
- 用途一:用于生化合成反应中基团保护及蛋白质肽链的连接
- Hazard Note:Irritant/Keep Cold/Moisture Sensitive
- 用途二:合成硫代酰胺的试剂；从醇中制备硫代甲酸酯，期间要和Bu3SnH-AIBN3剧烈反应。
- Acros Organics:1,1'-硫代羰酰二咪唑 1,1'-Thiocarbonyldiimidazole, tech., 90%(6160-65-2)
- Sigma Aldrich:6160-65-2(sigmaaldrich)
- N,N'-硫羰基二咪唑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010109 1，1-硫代羰基二咪唑 10g 600元 2011/04/16 C1376 1,1'-硫羰基二咪唑 1,1'-Thiocarbonyldiimidazole 5G 1020元 2011/04/16 C1376 1,1'-硫羰基二咪唑 1,1'-Thiocarbonyldiimidazole 25G 3050元
- TCI Shanghai:1,1'-硫羰基二咪唑 1,1'-Thiocarbonyldiimidazole,>;95.0%(T)(6160-65-2)
- MOL 文件:6160-65-2.mol
- MSDS 信息:1,1'-Thiocarbonylbis(imidazole)(6160-65-2).msds
