2-Chloro-5-Methylphenol 2-氯-5-甲基苯酚

CAS 615-74-7 MFCD00002175

化学结构图

615-74-7
SMILES: Cc1ccc(Cl)c(O)c1

化学属性

Mol. FormulaC₇H₇ClO
Mol. Weight142.58
Density1.215 g/mL at 25 °C(lit.)
Flash Point-
TSCAYes
Melting Point45-47ºC
Boiling Point-
Solubility不溶于水，溶于丙酮、苯、乙醚。

别名和识别编码

Chemical Name2-Chloro-5-Methylphenol
Synonym 2-CHLORO-5-METHYLPHENOL 2-CHLORO-5-METHYLPHENOL (6-CHLORO-M-CRESOL) 2-CHLORO-5-METHYLPHENOL, 1000MG, NEAT 2-Chlor-5-methyl-phenol 2-Chlor-5-methylphenol 2-Chloro-5-cresol 2-Chloro-5-methylphenol {Chemicalbook} 4-CHLORO-3-HYDROXYTOLUENE 4-CHLORO-5-HYDROXYTOLUENE 4-Chlor-3-hydroxytoluol 4-Chlor-5-hydroxytoluol 4-Chloro-3-hydroxytoluene 4-氯-3-羟基甲苯 42) 2-CHLORO-5-METHYL PHENOL (6-CHLORO META CRESOL) 5-Methyl-2-chlorophenol 6-CHLORO-M-CRESOL 6-CHLORO-META-CRESOL 6-Chlor-m
MDL Number-
CAS Number615-74-7
EC Number210-444-9
Beilstein Registry Number6(3)1315
PubChem Substance ID12008
Reaxys-RN2041487
Chemical Name Translation2-氯-5-甲基苯酚
LabNetwork Molecule IDLN00010015
InChIInChI=1S/C7H7ClO/c1-5-2-3-6(8)7(9)4-5/h2-4,9H,1H3
Canonical SMILES-
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • {SNA} Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment

相关文献及参考

  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/39 Title: Nuclear Quadrupole Resonance Spectroscopy Data Author: Chihara, H.; Nakamura, N. Editor: Chihara, H. Source: Landolt-Börnstein, New Series Volume: III/39 Year: 1997 Keyword: NQR; spectroscopy ISBN: 3-540-62428-7 ISBN: 978-3-540-62428-8 Internet Resource: DOI:10.1007/b61951 RefComment: VIII, 424 pages. Hardcover Abstract: Volume III/39 continues the compilation of nuclear quadrupole resonance spectroscopy data of solid substances which started in with volumes III/20 and III/31. The literature from the beginning of nuclear quadrupole resonance spectroscopy in 1951 to 1996 is covered. In total there are more than 10.000 substances in the volumes, showing the scope and significance of nuclear quadrupole resonance spectroscopy up to recent times. Volume III/39 can be consulted without recourse to its predecessor because the complete introduction and general tables are repeated from III/20 and III/31.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/e

安全信息

RTECSSK4930000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
Packing GroupII
UN Number UN3437 UN 3437 6.1/PG 2 3437
Risk Statements
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P302+P352+P332+P313+P362+P364
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P332+P313
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P305+P351+P338+P337+P313
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P302+P350
Signal word Warning
Hazard Codes Xi
Hazard Class6.1
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 562 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 562 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

Restrict 危险品
Storage condition 4°C

其他信息

  • 方法一:由间甲酚与次氯酸钠反应而得。在搅拌下，于30-40℃将间甲酚慢慢加入9.5%-10%次氯酸钠。加完后温度维持在30-40℃，搅拌1h，在日光下放置48h，加盐酸中和至呈酸性，分出油层，用1：1体积水洗涤，油层进行减压蒸馏，得该品。
  • 6-氯间甲酚 OR 3-甲基-6-氯苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0740 6-氯间甲酚 6-Chloro-m-cresol 25G 487元 2014/06/02 C0740 6-氯间甲酚 6-Chloro-m-cresol 5G 156元 2010/06/21 170411000 6-氯间甲酚 OR 3-甲基-6-氯苯酚 2-Chloro-5-methylphenol 99% 100 GR 1645元
  • 储运特性:库房通风低温干燥
  • 毒性分级:中毒
  • Alfa Aesar:2-氯-5-甲基苯酚,99% 2-Chloro-5-methylphenol, 99%(615-74-7)
  • MOL 文件:615-74-7.mol
  • 上游原料:氯酸钠 --> 间甲酚 --> 次氯酸
  • Sigma Aldrich:615-74-7(sigmaaldrich)
  • MSDS 信息:2-氯-5-甲酚(615-74-7).msds
  • 6-氯间甲酚 OR 3-甲基-6-氯苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 C0740 6-氯间甲酚 6-Chloro-m-cresol 25G 509元 2011/04/16 C0740 6-氯间甲酚 6-Chloro-m-cresol 5G 167元 2010/06/21 170411000 6-氯间甲酚 OR 3-甲基-6-氯苯酚 2-Chloro-5-methylphenol 99% 100 GR 1645元
  • 急性毒性:口服-鹌鹑 LD50: 562 毫克/公斤; 口服-野鸟 LD50: 562 毫克/公斤
  • 用途一:用于有机合成，影片防腐剂。
  • TCI Shanghai:6-氯-3-甲基苯酚 6-Chloro-m-cresol,>;99.0%(GC)(615-74-7)
  • 灭火剂:二氧化碳、砂土、泡沫、干粉
  • 图谱信息:6-氯间甲酚 OR 3-甲基-6-氯苯酚(615-74-7)红外图谱(IR2) 6-氯间甲酚 OR 3-甲基-6-氯苯酚(615-74-7)质谱(MS) 6-氯间甲酚 OR 3-甲基-6-氯苯酚(615-74-7)核磁图( 13 CNMR) 6-氯间甲酚 OR 3-甲基-6-氯苯酚(615-74-7)核磁图( 1 HNMR) 6-氯间甲酚 OR 3-甲基-6-氯苯酚(615-74-7)红外图谱(IR1) 6-氯间甲酚 OR 3-甲基-6-氯苯酚(615-74-7)Raman光谱
  • 可燃性危险特性:受热放出有毒氯化物气体
  • Acros Organics:2-氯-5-甲基苯酚 2-Chloro-5-methylphenol, 99%(615-74-7)
  • 外观性质:无色结晶，具有苯酚气味。
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  6. C6 to C8 - Phenols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers

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