Dimethyl L-(+)-Tartrate L-(+)-酒石酸二甲酯

CAS 608-68-4 MFCD00064437

化学结构图

608-68-4
SMILES: COC(=O)[C@H](O)[C@@H](O)C(=O)OC

化学属性

Mol. FormulaC6H10O6
Mol. Weight178.14
Density1.238
Boiling Point163 °C at 23 mmHg
Melting Point58 °C
Flash Point>170°(338°F)
TSCAYes
Refractive index21 ° (C=2.5, H2O)

别名和识别编码

Chemical NameDimethyl L-(+)-Tartrate
Synonym L-(+)-Tartaric acid dimethyl ester {LY} L-(+)-Tartaric acid dimethyl ester {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimethyl ester {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-(+)-Tartaric acid dimet
Beilstein Registry Number1726253
PubChem Substance ID87576032
CAS Number608-68-4
EC Number210-166-8
MDL NumberMFCD00064437
Reaxys-RN1726253
Chemical Name TranslationL-(+)-酒石酸二甲酯
InChIKeyPVRATXCXJDHJJN-QWWZWVQMSA-N
LabNetwork Molecule IDLN00153964
Canonical SMILESO=C([C@H](O)[C@@H](O)C(OC)=O)OC
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分类

  • {uni_hamburg} no charge; ester; alcohol; chiral; 1fragment
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Epoxidation, Esters, Organic Building Blocks
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Epoxidation, Esters, Organic Building Blocks

相关文献及参考

  • Short: IV/18B
  • Short: IV/1b
  • Short: EINECS
  • Has been used in Sharpless epoxidation of allylic alcohols; see tert-Butyl­ hydroperoxide, A13926.
  • Cyclic ketals formed with dimethyl tartrate as the diol component undergo highly selective bromination: Angew. Chem. Int. Ed., 25, 259 (1986).

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • L-(+)-酒石酸二甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0006 L-(+) -酒石酸二甲酯 Dimethyl L-(+)-Tartrate 25G 247元 2010/06/21 172490250 L-(+)-酒石酸二甲酯 (+)-Dimethyl L-tartrate 99% 25 GR 322元 2010/06/21 172491000 L-(+)-酒石酸二甲酯 (+)-Dimethyl L-tartrate 99% 100 GR 879元
  • 海关编码:29181300
  • Acros Organics:L-酒石酸二甲酯 (+)-Dimethyl L-tartrate, 99%(608-68-4)
  • MSDS 信息:L-(+)-Tartaric acid dimethyl ester(608-68-4).msds
  • TCI Shanghai:L-(+) -酒石酸二甲酯 Dimethyl L-(+)-Tartrate,>;98.0%(GC)(608-68-4)
  • 用途一:主要用于手性药物、手性中间体的合成及不对称催化领域
  • Sigma Aldrich:608-68-4(sigmaaldrich)
  • MOL 文件:608-68-4.mol
  • Alfa Aesar:L-(+)酒石酸二甲酯,99% Dimethyl L-tartrate, 99%(608-68-4)
  • 图谱信息:L-(+)-酒石酸二甲酯(608-68-4)核磁图( 13 CNMR) L-(+)-酒石酸二甲酯(608-68-4)红外图谱(IR2) L-(+)-酒石酸二甲酯(608-68-4)红外图谱(IR3) L-(+)-酒石酸二甲酯(608-68-4)红外图谱(IR1) L-(+)-酒石酸二甲酯(608-68-4)Raman光谱 L-(+)-酒石酸二甲酯(608-68-4)核磁图( 1 HNMR) L-(+)-酒石酸二甲酯(608-68-4)质谱(MS)
  • 比旋光度:21 ° (c=10, H2O)
  • 下游产品:

系列性分类


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