CAS 602-87-9 MFCD00014277-5-Nitroacenaphthene (Contains 3-Nitroacenaphthene) TAO{mole}

5-Nitroacenaphthene (Contains 3-Nitroacenaphthene)

CAS 602-87-9 MFCD00014277

化学结构图

SMILES: O=[N+]([O-])c1ccc2c3c(cccc13)CC2

化学属性

Mol. Formula	C₁₂H₉NO₂
Mol. Weight	199.21
Melting Point	98-103°C
TSCA	Yes
Boiling Point	-
Flash Point	-
Solubility	溶于醇、醚、油类、热水。

别名和识别编码

Chemical Name	5-Nitroacenaphthene
Synonym	1,2-Dihydro-5-nitro-acenaphthylene 1,2-Dihydro-5-nitroacenaphthylene 1,2-dihydro-5-nitro-acenaphthylen 1,2-dihydro-5-nitroacenaphthylene 1,2-二氢-5-硝基苊 1,2-二氢-5-硝基苊,5-硝基苊 5-NITROACENAPHTHENE 5-Nan 5-Nitro-1,2-dihydroacenaphthylene 5-Nitroacenaphthene {} {} {} {} {} {Chemicalbook} Nitroacenaphthene {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} NCI-C01967 {} {} {} {} {} {} {} {uni_hamburg} Acenaphthylene, 1,2-dihydro-5-nitro- {} {} {} {} {} {} {} {} {uni_hamburg} Acenaphthene, 5-nitro- {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} 5-硝基苊 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} 5-硝基二氢苊 {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} 5-nitronaphthaleneethylene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {PubChem} 5-nitroacenaphthene
MDL Number	-
CAS Number	602-87-9
EC Number	210-025-0
Beilstein Registry Number	5(4)1840
PubChem Substance ID	11769
Reaxys-RN	1876864
Chemical Name Translation	(Contains 3-Nitroacenaphthene)
Wiswesser Line Notation	L566 1A LT&&J HNW
LabNetwork Molecule ID	LN00248377
InChI	InChI=1S/C12H9NO2/c14-13(15)11-7-6-9-5-4-8-2-1-3-10(11)12(8)9/h1-3,6-7H,4-5H2
Canonical SMILES	-

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产品应用

该品是染料酸性高黄 FF；分散荧光黄等的中间体。也用作光刻胶增感剂。

安全信息

RTECSAB1060000

Safety Statements

Risk Statements

R45 May cause cancer 可能致癌

WGK Germany3

GHS Symbol

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P308+P313
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P501a

Hazard statements

H350 May cause cancer 可能致癌
H351 Suspected of causing cancer 怀疑致癌

Signal word

Personal Protective Equipment Eyeshields, Gloves, type P2 (EN 143) respirator cartridges

Hazard Codes T T,Xi

UN Number 2811

Packing GroupIII

Hazard Class6.1

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3744 mg/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Blood - leukemia
   Blood - lymphoma, including Hodg

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 120 gm/kg/17W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Gastrointestinal - tumors
   Skin and Appendages - tumors
REFERENCE :
   TJIDAH Tokyo Jikeikai Ika Daigaku Zasshi.  Tokyo Jikeikai Medical Journal.
   (3-25-8, Nishi Shinbashi, Minato-ku, Tokyo 105, Japan)  V.66-    1951-
   Volume(issue)/page/year: 89,475,1974

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 60 gm/kg/70W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Sense Organs and Special Senses (Ear) - effect, not otherwise specified
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-118,1978

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 80 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Reproductive - Tumorigenic effects - ovarian tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/

TY

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - mouse Liver
DOSE/DURATION           : 200 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 190,159,1987

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 20 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 190,159,1987

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 30 ng/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7(Suppl
   5),1,1985

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 300 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 272,91,1992

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7(Suppl
   5),1,1985

Storage condition -20°C

其他信息

TCI Shanghai:5-硝基苊(含3-硝基苊) 5-Nitroacenaphthene (contains 3-Nitroacenaphthene),>;80.0%(GC)(602-87-9)
下游产品:
Hazard Note:Irritant
方法一:由苊硝化而得。在干燥的搪玻璃反应锅中加入冰醋酸，在搅拌下加入工业苊（熔点92-94℃）。加热至70℃搅拌10min，冷却至23℃。控制温度23-26℃之间并慢慢滴加65%硝酸。加毕，在23-26℃下搅拌1h即生成5-硝基苊。
MSDS 信息:硝基苊(602-87-9).msds
上游原料:搪玻璃反应锅 --> 苊
用途三:该品是染料酸性高黄 FF；分散荧光黄等的中间体。也用作光刻胶增感剂。
Sigma Aldrich:602-87-9(sigmaaldrich)
Alfa Aesar:5-硝基苊,98% 5-Nitroacenaphthene, 98%(602-87-9)
外观性质:黄色针状结晶。
用途二:该品是染料酸性高黄 FF、分散荧光黄等的中间体。也用作光刻胶增感剂。
溶于热水、乙醇、乙醚和石油醚。遇浓硫酸呈蓝紫色。
用途一:用作化学试剂
MOL 文件:602-87-9.mol
图谱信息:1,2-二氢-5-硝基苊 (602-87-9)红外图谱(IR1) 1,2-二氢-5-硝基苊 (602-87-9)红外图谱(IR2) 1,2-二氢-5-硝基苊 (602-87-9)质谱(MS)