Trimethyl phosphonoacetate 磷酰基乙酸三甲酯
CAS 5927-18-4 MFCD00008452
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资金保障
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信息真实价格透明
资金保障
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents
相关文献及参考
- Horner-Wadsworth-Emmons olefination (see Appendix 1) with aldehydes and ketones gives acrylic esters, cf Triethyl phosphonoacetate, A14120. In general, the (E):(Z) ratio of the resulting alkene increases as the counter-ion becomes smaller (K, Na, Li) and as the temperature increases. See, e.g.: J. Org. Chem., 55, 3386 (1990). Reaction with ɑ-hydroxy ketones provides a simple route to butenolides: Tetrahedron Lett., 36, 2839 (1995):
安全信息
GHS Symbol
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P332+P313
- P305+P351+P338+P337+P313
- P302+P350
- P337+P313
- P302+P352+P332+P313+P362
- H227 Combustible liquid 可燃液体
其他信息
- TCI Shanghai:膦酰乙酸三甲酯 Trimethyl Phosphonoacetate,>;96.0%(GC)(5927-18-4)
- 海关编码:29310095
- Acros Organics:磷乙酸三甲酯 Trimethyl phosphonoacetate, 98%(5927-18-4)
- 用途一:为一类重要的Wittig-horner试剂,也是用于制造维生素类化合物、药物、昆虫信息素等天然化合物的重要中间体。
- F:9
- 三甲基膦酰基乙酸酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1265 膦酰乙酸三甲酯 Trimethyl Phosphonoacetate 25G 423元 2014/06/02 P1265 膦酰乙酸三甲酯 Trimethyl Phosphonoacetate 250G 2070元 2010/06/21 140231000 三甲基膦酰基乙酸酯 Trimethyl phosphonoacetate 98% 100 GR 1143元
- 下游产品:3-甲氧基羰基-3-亚砜
- MSDS 信息:(Dimethoxyphosphinyl)-acetic acid methyl ester(5927-18-4).msds
- MOL 文件:5927-18-4.mol
- Alfa Aesar:磷酸乙酸三甲酯,98% Trimethyl phosphonoacetate, 98%(5927-18-4)
- Sigma Aldrich:5927-18-4(sigmaaldrich)