CAS 589-92-4 MFCD00001643-4-Methylcyclohexanone 4-甲基环己酮 TAO{mole}

4-Methylcyclohexanone 4-甲基环己酮

CAS 589-92-4 MFCD00001643

化学结构图

SMILES: CC1CCC(=O)CC1

化学属性

Mol. Formula	C7H12O
Mol. Weight	112.17
Refractive index	1.4420 to 1.4480
Boiling Point	170°C at 760 mmHg
Density	0.914
Flash Point	48°C
TSCA	Yes
Melting Point	-41°C
Appearance	无色液体，有丙酮味。熔点-40.6℃，沸点170℃，相对密度 20/4℃ 0.914，折光率1.4451，75℃时遇硝酸可爆炸。闪点48℃。溶于醇、醚，不溶于水。

别名和识别编码

Chemical Name	4-methylcyclohexan-1-one
Synonym	4-Methylcyclohexanone {LY} 4-Methylcyclohexanone {} {LY} 4-Methylcyclohexanone {} {} {LY} 4-Methylcyclohexanone {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Meth
CAS Number	589-92-4
PubChem Substance ID	11525
EC Number	209-665-3
Beilstein Registry Number	506746
MDL Number	MFCD00001643
Reaxys-RN	506746
Chemical Name Translation	4-甲基环己酮
LabNetwork Molecule ID	LN00335098
InChI	InChI=1S/C7H12O/c1-6-2-4-7(8)5-3-6/h6H,2-5H2,1H3
Canonical SMILES	O=C1CCC(C)CC1

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

甲环亚硝脲的中间体,亦可用作溶剂。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H302 Harmful if swallowed 吞食有害
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H318 Causes serious eye damage 严重伤害眼睛

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 3

RTECSGW1750200

Signal word Warning

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Risk Statements

R10 Flammable 易燃
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P211 Do not spray on an open flame or other ignition source.? 不要喷洒在明火或其他点火源。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P310
P301+P316
P301+P317
P301+P330+P331
P302+P352
P302+P361+P354
P303+P361+P353
P304+P340
P305+P351+P338
P305+P351+P338+P337+P313
P305+P354+P338
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P316
P317
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P331 Do NOT induce vomiting.. 不要催吐。
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P403+P233
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

UN Number 2297 UN 2297 3/PG 3

Packing GroupIII

Hazard Class3

Storage condition 2-8°C {LY} 2-8°C Flammables area {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 370 mg/kg
TOXIC EFFECTS :
   Cardiac - change in rate
   Vascular - BP lowering not characterized in autonomic section
REFERENCE :
   COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences.
   (Paris, France)  V.1-261, 1835-1965.  For publisher information, see CRASEV.
    Volume(issue)/page/year: 236,633,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton,
   G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82.
   Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985.
   Volume(issue)/page/year: 2C,4783,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton,
   G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82.
   Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985.
   Volume(issue)/page/year: 2C,4783,1982

其他信息

4-甲基环己酮价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 K6640002 4-甲基环己酮 100ml 1158元 2011/04/16 M0199 4-甲基环己酮 4-Methylcyclohexanone 500ML 2290元 2011/04/16 M0199 4-甲基环己酮 4-Methylcyclohexanone 25ML 275元
Sigma Aldrich:589-92-4(sigmaaldrich)
MSDS 信息:4-Methylcyclohexanone(589-92-4).msds
有丙酮味,溶于醇、醚，不溶于水。
海关编码:29142200
方法一:由甲基环己醇氧化制得。
用途二:甲环亚硝脲的中间体,亦可用作溶剂。
MOL 文件:589-92-4.mol
用途一:甲环亚硝脲的中间体。亦可用作溶剂。
Hazard Note:Irritant
Acros Organics:4-甲基环己酮 4-Methylcyclohexanone, 98%(589-92-4)
TCI Shanghai:4-甲基环己酮 4-Methylcyclohexanone,>;98.0%(GC)(589-92-4)
下游产品:2-氨基-6-甲基-4,5,6,7-四氢-1-苯并噻吩-3-腈 --> 2-氨基-6-甲基-4,5,6,7-四氢-苯并噻吩-3-甲酸乙酯 --> 2-氨基-6-甲基-4,5,6,7-四氢-1-苯并噻吩-3-甲酰胺
图谱信息:4-甲基环己酮(589-92-4)质谱(MS) 4-甲基环己酮(589-92-4)核磁图( 1 HNMR) 4-甲基环己酮(589-92-4)核磁图( 13 CNMR) 4-甲基环己酮(589-92-4)Raman光谱 4-甲基环己酮(589-92-4)红外图谱(IR1)
Alfa Aesar:4-甲基环己酮,98+% 4-Methylcyclohexanone, 98+%(589-92-4)
FEMA:3948