2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈
CAS 58632-95-4 MFCD00001863
化学结构图
SMILES: CC(C)(C)OC(=O)O/N=C(\C#N)c1ccccc1
化学属性
| Mol. Formula | C13H14N2O3 |
|---|---|
| Mol. Weight | 246 |
| Melting Point | 85-88 |
| Density | 1.422 |
| TSCA | Yes |
| Solubility | insoluble |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | 2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile |
|---|---|
| Synonym | 2-(BOC-OXYIMINO)-2-PHENYLACETONITRILE 2-(Boc-oxyimino)-2-phenylacetonitrile 2-(Boc-oxyimino)-2-phenylacetonitrile~2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile 2-(T-BUTOXYCARBONYLOXYIMINO)-2-PHENYLACETONITRILE 2-(叔-丁氧基碳酰胺)-2-苯乙腈, 98+% 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈 2-(叔丁氧羰基氧亚氨基)-2-苯基乙腈 2-T-BUTYLOXYCARBONYLOXYIMINO-2-PHENYL ACETONITRILE BOC-ON Boc-ON 2-t-Butyloxycarbonyloxyimino-2-phenyl acetonitrile Boc-ON, 98+% LABOTEST-BB LT00159655 N-TERT-BUTOXYCARBONYLOXYIMINO-2-PHENYLACETONITRILE [(CYANO-PHENYL-METHYLIDENE)AMINO] TERT-BUTYL CARBONATE tert-butyl alpha-cyanobenzylaminyl carbonate 叔丁基 叔丁基苯乙腈肟羰酸酯 |
| Beilstein Registry Number | 2217296 |
| PubChem Substance ID | 87563941 |
| CAS Number | 58632-95-4 |
| EC Number | 261-370-9 |
| MDL Number | MFCD00001863 |
| Reaxys-RN | 2217296 |
| Chemical Name Translation | 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈 |
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分类
- {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
- {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Other Protecting and Derivatizing Reagents, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
- Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
产品应用
- 肽合成中的氨基保护试剂。
相关文献及参考
- Aldrich MSDS 1 , 211:C / Corp MSDS 1 (1), 469:B / FT-IR 2 (2), 3117:A / FT-IR 1 (2), 317:D / FT-NMR 1 (2), 1486:C / IR-Spectra (3), 1041:D / RegBook 1 (2), 2109:H / Sigma FT-IR 1 (2), 351:A / Structure Index 1 , 333:C:6
- Fieser 6 ,91 / Fieser 10 ,61
- Merck 14 ,10432
- Reagent for the preparation of Boc-derivatives of amino acids, preferred on safety grounds to the unstable t-butyl azidoformate. In aqueous dioxane and in the presence of triethylamine as base, reaction is rapid at room temperature. The organic by-product, 2-hydroxyimino-2-phenylacetonitrile is easily removed by extraction into an organic phase: Tetrahedron Lett., 4393 (1975); Bull. Chem. Soc. Jpn., 50, 718 (1977). See Appendix 6.
安全信息
GHS Symbol
- S22 Do not breathe dust 不要吸入粉尘；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310+P330
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P332+P313
- P302+P352+P332+P313+P362+P364
- P405 Store locked up. 上锁保管。
- P305+P351+P338+P337+P313
- H301 Toxic if swallowed 吞食有毒
其他信息
- 下游产品:2-(甲基氨基)乙基氨基甲酸叔丁酯
- 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B0988 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈 2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile 25G 1220元 2011/04/16 B0988 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈 2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile 5G 366元 2010/06/21 185890250 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈 BOC-ON 99% 25 GR 1649元
- MSDS 信息:2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile(58632-95-4).msds
- Alfa Aesar:2-(叔-丁氧基碳酰胺)-2-苯乙腈,98+% Boc-ON, 98+%(58632-95-4)
- MOL 文件:58632-95-4.mol
- TCI Shanghai:2-(叔丁氧羰基氧亚氨基)-2-苯乙腈 2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile,>;98.0%(T)(58632-95-4)
- Acros Organics:2-(叔-丁氧基碳酰胺)-2-苯乙腈 BOC-ON, 99%(58632-95-4)
- Sigma Aldrich:58632-95-4(sigmaaldrich)
- F:10-21
- 海关编码:29280090
- 敏感性:Moisture Sensitive
