CAS 57090-45-6 MFCD00135169-(R)-(-)-3-Chloro-1,2-Propanediol (R)-3-氯-1,2-丙二醇 TAO{mole}

(R)-(-)-3-Chloro-1,2-Propanediol (R)-3-氯-1,2-丙二醇

CAS 57090-45-6 MFCD00135169

化学结构图

SMILES: OC[C@@H](O)CCl |&1:2|

化学属性

Mol. Formula	C3H7ClO2
Mol. Weight	111
Density	1.321
Refractive index	1.4790 to 1.4830
Flash Point	126°C(lit.)
TSCA	No
Boiling Point	213
Vapor Pressure	0.04 mmHg ( 25 °C)
Appearance	无色至淡黄色液体，常温下在密闭的容器内保存。沸点213°C。
Melting Point	-40°C
Solubility	soluble

别名和识别编码

Chemical Name	(R)-(-)-3-Chloro-1,2-Propanediol
CAS Number	57090-45-6
Alfabeta Name	CHLOROPROPANEDIOL R312()----,
MDL Number	MFCD00135169
EC Number	435-560-9
Beilstein Registry Number	2202928
Synonym	(-)-α-monochlorohydrine (R)-(- (R)-(-)--Chlorohydrin (R)-(-)-3-CHLORO-1,2-PROPANEDIOL (R)-(-)-3-Chloro-1,2-propanediol, 97%, ee 98% (R)-(-)-3-氯-1,2-丙二醇 (R)-(-)-3-氯-1,2-丙二醇, 97%, E (R)-(-)-ALPHA-CHLOROHYDRIN (R)-(-)-ALPHA-MONOCHLOROHYDRIN (R)-(-)-α-Chlorohydrin (R)-3-CHLORO-1,2-PROPANEDIOL (R)-3-CHLORO-1,2-PROPANEDIOL ,98%MIN (R)-3-CHLOROPROPANE-1,2-DIOL (R)-3-氯-1,2-丙二醇 (R)-ALPHA-GLYCEROL CHLOROHYDRIN (R)-GLYCEROL ALPHA-MONOCHLOROHYDRIN (R)-α-Glycerol chlorohydrin )-3-Chloro-1,2-propanediol 3-氯-1,2-丙二醇（右旋体） ?-(-)-3-氯-1,2-丙二醇 GLYCEROL (R)-(-)-ALPHA-M R-3-氯-1,2-丙二醇 R-Chloropropanediol 左旋3-氯-1,2-丙二醇
PubChem Substance ID	87572947
Chemical Name Translation	(R)-3-氯-1,2-丙二醇
Reaxys-RN	2202928
InChIKey	SSZWWUDQMAHNAQ-VKHMYHEASA-N
LabNetwork Molecule ID	LN00173957

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安全信息

Warnings IRRITANT

RTECSTY4025000

UN Number 2689

Risk Statements

R21 Harmful in contact with skin 与皮肤接触有害
R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
R25 Toxic if swallowed 吞咽有毒
R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
R60 May impair fertility 可能降低生殖能力
R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险

Safety Statements

S20 When using do not eat or drink 使用时，不得进食，饮水；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S39 Wear eye/face protection 戴眼睛/面孔保护装置；
S4 Keep away from living quarters 远离生活区；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；

GHS Symbol

WGK Germany3

Hazard statements

H318 Causes serious eye damage 严重伤害眼睛
H301 Toxic if swallowed 吞食有毒
H300 Fatal if swallowed 吞食致命

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 6.1 T

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P302+P350
P302+P352+P312+P361+P364
P304 IF INHALED: 如果吸入
P305+P351+P338
P305+P351+P338+P310
P308+P313
P332+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Packing GroupIII

Hazard Class6.1

Storage condition 2-8°C

其他信息

MSDS 信息:(R)-(-)-3-Glycerol alpha-monochlorohydrin(57090-45-6).msds
用途三:化工、有机化工原料、有机中间体、医药中间体。
用途二:多种手性医药中间体。
F:3
Alfa Aesar:(R)-(-)-3-氯-1,2-丙二醇,97%,ee98% (R)-(-)-3-Chloro-1,2-propanediol, 97%, ee 98%(57090-45-6)
(R)-3-氯-1,2-丙二醇价格(试剂级):更新日期产品编号产品名称包装价格 2011/04/16 M0967 (R)-(-)-3-氯-1,2-丙二醇 (R)-(-)-3-Chloro-1,2-propanediol 25G 1190元 2011/04/16 M0967 (R)-(-)-3-氯-1,2-丙二醇 (R)-(-)-3-Chloro-1,2-propanediol 10G 686元
TCI Shanghai:(R)-(-)-3-氯-1,2-丙二醇 (R)-(-)-3-Chloro-1,2-propanediol,>;96.0%(GC)(57090-45-6)
MOL 文件:57090-45-6.mol
用途一:用于合成手性试剂及医药中间体
蒸气压:0.04 mm Hg ( 25 °C)
Sigma Aldrich:57090-45-6(sigmaaldrich)
比旋光度:-0.9 ° (neat)