Z-L-Glu-OMe N-苄氧羰基-L-谷氨酸-1-甲酯

CAS 5672-83-3 MFCD00083278

化学结构图

5672-83-3
SMILES: COC(=O)[C@H](CCC(=O)O)NC(=O)OCc1ccccc1

化学属性

Mol. FormulaC14H17NO6
Mol. Weight295.29
Melting Point68-70°C
Refractive index1.4365
TSCANo
Density1.272
Boiling Point436.98 °C at 760 mmHg

别名和识别编码

Chemical NameZ-L-Glu-OMe
MDL NumberMFCD00083278
CAS Number5672-83-3
Synonym N-Benzyloxycarbonyl-L-glutamic acid 1-methyl ester {LY} N-Benzyloxycarbonyl-L-glutamic acid 1-methyl ester {} {LY} N-Benzyloxycarbonyl-L-glutamic acid 1-methyl ester {} {} {LY} N-Benzyloxycarbonyl-L-glutamic acid 1-methyl ester {} {} {} {LY} N-Benzyloxycarbonyl-L-glutamic acid 1-methyl ester {} {} {} {} {LY} N-Benzyloxycarbonyl-L-glutamic acid 1-methyl ester {} {} {} {} {} {LY} N-Benzyloxycarbonyl-L-glutamic acid 1-methyl ester {} {} {} {} {} {} {LY} N-Benzyloxycarbonyl-L-glutamic acid 1-methyl ester {} {} {} {} {} {} {} {LY} N-Benzyloxycarbonyl-L-glutamic acid 1-methyl ester {} {} {} {} {} {} {} {} {LY} N-Benzyloxycarbonyl-L-glutamic acid 1-methyl ester {} {} {} {} {} {} {} {} {} {LY} N-Benzyloxycarbonyl-L-glutamic acid 1-methyl ester {} {} {} {} {} {} {} {} {} {} {LY} N-Benzyloxycarbonyl-L-glutamic acid 1-methyl ester {} {} {} {} {} {} {} {} {} {} {} {LY} N-Benzyloxycarbonyl-L-glutamic acid 1-methyl ester {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Benzyloxycarbony
Beilstein Registry Number2567599
PubChem Substance ID2733408
Reaxys-RN2567599
EC Number250-023-7
Chemical Name TranslationN-苄氧羰基-L-谷氨酸-1-甲酯
LabNetwork Molecule IDLN01363784
InChIInChI=1S/C14H17NO6/c1-20-13(18)11(7-8-12(16)17)15-14(19)21-9-10-5-3-2-4-6-10/h2-6,11H,7-9H2,1H3,(H,15,19)(H,16,17)/t11-/m0/s1
Canonical SMILESO=C(O)CC[C@@H](C(OC)=O)NC(OCC1=CC=CC=C1)=O
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分类

  • {SNA} Amino Acid Derivatives, Chemical Biology, Chemical Synthesis, Glutamic Acid, Peptide Chemistry
  • {SNA} Amino Acids & Derivatives, Chemical Biology, Chemical Synthesis, Glutamic Acid, Peptide Chemistry

相关文献及参考

  • Beilstein:6(3)1516

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Signal word Warning
GHS Symbol
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P317
  • P337+P317
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激

系列性分类

  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Glutamic Acid - Amino Acid Derivatives
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Glutamic Acid - Amino Acid Derivatives
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  4. Modified Amino Acids - Amino Acids
  5. Cbz-amino Acids

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