CAS 564483-18-7 MFCD04117682-2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl 2-二环己基磷-2′,4′,6′-三异丙基-1,1′-联苯 TAO{mole}

2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl 2-二环己基磷-2′,4′,6′-三异丙基-1,1′-联苯

CAS 564483-18-7 MFCD04117682

化学结构图

SMILES: CC(C)c1cc(C(C)C)c(-c2ccccc2P(c2ccccc2)c2ccccc2)c(C(C)C)c1

化学属性

Mol. Formula	C33H49P
Mol. Weight	476.73
Melting Point	186.0 to 190.0 deg-C
TSCA	No
Stability	对空气敏感
Appearance	white pwdr.
Boiling Point	569.8°C at 760 mmHg
Danger-Level	-
pH	-:-
Redox	-

别名和识别编码

Chemical Name	2-(Dicyclohexylphosphino)-2,4,6-Triisopropylbiphenyl
CAS Number	564483-18-7
Alfabeta Name	DICYCLOHEXYLPHOSPHINOTRIPROPYLBIPHENYL I224611()-------,,,''''
MDL Number	MFCD04117682
Synonym	XPhos {LY} XPhos {} {LY} XPhos {} {} {LY} XPhos {} {} {} {LY} XPhos {} {} {} {} {LY} XPhos {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos
PubChem Substance ID	11155794
Chemical Name Translation	2-二环己基磷-2′,4′,6′-三异丙基-1,1′-联苯
LabNetwork Molecule ID	LN00155082
Reaxys-RN	9448497
InChI	InChI=1S/C33H49P/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3
Canonical SMILES	CC(C)C1=CC(C(C)C)=CC(C(C)C)=C1C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

Warnings IRRITANT, AIR SENSITIVE

WGK Germany3

GHS Symbol

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P312
P302+P352
P302+P352+P332+P313+P362+P364
P304+P340
P305+P351+P338
P305+P351+P338+P337+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H302 Harmful if swallowed 吞食有害
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H351 Suspected of causing cancer 怀疑致癌
H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。

Signal word Warning

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

Safety Statements

S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37 Wear suitable gloves 戴适当手套；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R22 Harmful if swallowed 吞咽有害
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用

Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from lig

Hazard Codes Xn

Restrict -

其他信息

Sigma Aldrich:564483-18-7(sigmaaldrich)
Alfa Aesar:2-双环己基膦-2',4',6'-三异丙基联苯,98+% 2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 98+%(564483-18-7)
上游原料:乙酸乙酯 --> 甲醇 --> 四氢呋喃 --> 二氯甲烷 --> 溴 --> 四氯化碳 --> 铁粉 --> 镁 --> 氯化亚铜 --> 1,4-苯二酚 --> 1,3,5-三异丙基苯 --> 2-溴氯苯 --> 二环己基氯化膦
MOL 文件:564483-18-7.mol
敏感性:Air Sensitive
用途一:偶联反应中，催化体系中配体成份
2-二环己基磷-2,4,6-三异丙基联苯价格(试剂级):更新日期产品编号产品名称包装价格 2010/06/21 387140010 2-二环己基磷-2,4,6-三异丙基联苯 2-(Dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl 98+% 1 GR 708元 2010/06/21 387140050 2-二环己基磷-2,4,6-三异丙基联苯 2-(Dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl 98+% 5 GR 2939元 2010/06/21 387140250 2-二环己基磷-2,4,6-三异丙基联苯 2-(Dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl 98+% 25 GR 10871元
Acros Organics:2-(二环己基磷)-2',4',6'-三异丙基联苯 2-(Dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl(564483-18-7)