CAS 563-76-8 MFCD00000142-2-Bromopropionyl bromide 2-溴丙酰溴 TAO{mole}

2-Bromopropionyl bromide 2-溴丙酰溴

CAS 563-76-8 MFCD00000142

化学结构图

SMILES: CC(Br)C(=O)Br

化学属性

Mol. Formula	C3H4Br2O
Mol. Weight	216
Density	2.061
Refractive index	1.5180 to 1.5220
Vapor Density	7.5 (vs air)
Boiling Point	48-50
Vapor Pressure	1.3 mmHg ( 20 °C)
Flash Point	109°C(lit.)
TSCA	Yes
Solubility	可混溶于乙酸、苯等。
Stability	易吸潮

别名和识别编码

Chemical Name	2-Bromopropionyl bromide
CAS Number	563-76-8
EC Number	209-261-7
Beilstein Registry Number	1071331
MDL Number	MFCD00000142
PubChem Substance ID	79047
Synonym	-Bromopropionylbromide ALPHA-BROMOPROPIONYL BROMIDE 2-Bromopropionic acid bromide 2-bromo-Propanoylbromide 溴化-2-溴丙酰 2-Bromopropanoyl bromide 2-Bromopropiomyl bromide 1,2-Dibromo-2-propanone 2-溴丙酰溴 2-Bromopropanoic acid bromide 2-BROMOPROPIONYL BROMIDE 98.5% 2-bromo-propanoylbromid 2-BROMOPROPIONYL BROMIDE (ALPHA-) Propanoyl bromide, 2-bromo- 2-BROMOPROPIONYL BROMIDE
Reaxys-RN	1071331
Chemical Name Translation	2-溴丙酰溴
InChIKey	ILLHORFDXDLILE-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00193077
InChI	InChI=1S/C3H4Br2O/c1-2(4)3(5)6/h2H,1H3

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产品应用

为麻醉药类γ-羰基丁酸钠的中间体，也是医药丙胺卡因中间体。

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S20 When using do not eat or drink 使用时，不得进食，饮水；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R34 Causes burns 会导致灼伤
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P234 Keep only in original container. 只保留在原来的容器中。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312
P301+P317
P301+P330+P331
P301+P330+P331+P310
P302+P361+P354
P303+P361+P353
P303+P361+P353+P310+P363
P304+P340
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P305+P354+P338
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P316
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H290 May be corrosive to metals 可能腐蚀金属。
H302 Harmful if swallowed 吞食有害
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Packing GroupII

UN Number 3265 UN 3265 8/PG 2 UN3265

Storage condition Moisture Sensitive 易吸潮，密封避光保存

Hazard Codes 8 C

Hazard Class8

Warnings 危化品目录(2015)

Restrict 危险品

其他信息

外观性质:无色或浅黄色液体。
用途二:为麻醉药类γ-羰基丁酸钠的中间体，也是医药丙胺卡因中间体。
用途一:用作医药、农药中间体
MOL 文件:563-76-8.mol
Alfa Aesar:2-溴丙酰溴,97% 2-Bromopropionyl bromide, 97%(563-76-8)
2-溴丙酰溴价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 xw010365 2-溴丙酰溴 50ml 168元 2011/04/16 B0649 2-溴丙酰溴 2-Bromopropionyl Bromide 500G 1540元 2011/04/16 B0649 2-溴丙酰溴 2-Bromopropionyl Bromide 25G 200元
存储注意事项:湿度敏感
方法一:由丙酸溴化而得。将丙酸和赤磷加入反应锅内，在60℃滴加溴素，约3h加完，升温至100-120℃，保温反应6h。冷却，过滤，滤液常压分馏，154℃以前的馏分为低沸物，稍冷，减压收集高沸点馏分直至蒸不出为止，得2-溴丙酰溴。
能与苯、乙酸、丙酸混溶。遇水及醇分解。
蒸气密度:7.5 (vs air)
蒸气压:1.3 mm Hg ( 20 °C)
TCI Shanghai:2-溴丙酰溴 2-Bromopropionyl Bromide,>;98.0%(T)(563-76-8)
Sigma Aldrich:563-76-8(sigmaaldrich)
敏感性:Moisture Sensitive
上游原料:溴
MSDS 信息:2-溴丙酰溴(563-76-8).msds