Allyl Ether 烯丙基醚

CAS 557-40-4 MFCD00008650

化学结构图

557-40-4
SMILES: C=CCOCC=C

化学属性

Mol. FormulaC6H10O
Mol. Weight98.14
Refractive index1.4150 to 1.4180
Boiling Point
Density0.803 g/mL at 25 °C(lit.)
Flash Point-7°C(lit.)
Solubility不溶
Melting PointNo Data Available

别名和识别编码

Chemical NameAllyl Ether
Synonym 1-Propene, 3,3'-oxybis- 1-Propene, 3,3'-oxybis- 1-乙烯基-2-吡咯烷酮 3,3'-Oxybis(1-propen) 3,3'-Oxybis(1-propene) 3,3'-Oxybis-1-propene 3,3'-OXYBIS(1-PROPENE) 3,3'-Oxybis(1-propene) 3,3’-oxybis-1-propen 3-(Allyloxy)-1-propene 4-Oxahepta-1,6-diene ALLYL ETHER Allyl Ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number557-40-4
PubChem Substance ID87561890
EC Number209-174-4
MDL NumberMFCD00008650
Reaxys-RN1736015
Merck Number292
Beilstein Registry Number1(4)2086
Chemical Name Translation烯丙基醚
Wiswesser Line Notation1U2O2U1
LabNetwork Molecule IDLN01739878
InChIInChI=1S/C6H10O/c1-3-5-7-6-4-2/h3-4H,1-2,5-6H2
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分类

  • {uni_hamburg} no charge; ether; 1fragment
  • Allyl Monomers, Materials Science, Monomers, Polymer Science
  • {SNA} Allyl Monomers, Monomers, Polymer Science, 材料科学
  • {SA} Allyl Monomers, Materials Science, Monomers, Polymer Science

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communitie
  • Aldrich MSDS 1 , 44:B / Corp MSDS 1 (1), 100:B / FT-IR 2 (1), 318:A / FT-IR 1 (1), 212:D / FT-NMR 1 (1), 333:C / RegBook 1 (1), 219:H / Sax 6 , 878 / Structure Index 1 , 30:C:5 / Vapor Phase 3 , 279:B
  • Merck 14 ,292
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/8H Title: Densities of Esters and Ethers Author: Frenkel, M.; Hong, X.; Wilhoit, R.C.; Hall, K.R. Editor: Hall, K.R.; Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8H Year: 2001 Keyword: organic compounds; density; liquids ISBN: 3-540-41035-X ISBN: 978-3-540-41035-5 Internet Resource: DOI:10.1007/b76770 RefComment: XI, 484 pages, with CD-ROM, Hardcover
  • Beil. 1 ,438
  • Short: IV/18B Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18B Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures Internet Resource: DOI:10.1007/b68240 RefComment: VII, 409 pages.

安全信息

GHS Symbol
WGK Germany3
Hazard Codes F,Xn Xn-F,Xn,F F;Xn
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSKN7525000
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P332+P313
  • P301+P312+P330
  • P337+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P403+P235
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P305+P351+P338+P337+P313
  • P241+P242+P243
  • P302+P352+P312+P361+P364
  • P405 Store locked up. 上锁保管。
  • P233 Keep container tightly closed. ?保持容器密闭。
Signal word Danger
UN Number 2360
Packing GroupII
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Hazard Class3/6.1
Storage condition +4°C 4 4℃ Refrigerator (+4°C) + Flammables area
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 63,1068,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,60,1949

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 3,362,1951

其他信息

  • MOL 文件:557-40-4.mol
  • Acros Organics:乙烯基醚 Allyl ether, 99%(557-40-4)
  • 刺激数据:皮肤- 兔子 500 毫克/ 24小时 轻度; 眼睛- 兔子 100 毫克/ 24小时 中度
  • 毒性分级:高毒
  • Sigma Aldrich:557-40-4(sigmaaldrich)
  • 图谱信息:烯丙基醚(557-40-4)红外图谱(IR2) 烯丙基醚(557-40-4)核磁图( 13 CNMR) 烯丙基醚(557-40-4)红外图谱(IR1) 烯丙基醚(557-40-4)Raman光谱 烯丙基醚(557-40-4)核磁图( 1 HNMR) 烯丙基醚(557-40-4)质谱(MS)
  • 类别:易燃液体
  • 烯丙基醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0229 烯丙基醚 Allyl Ether 500ML 4380元 2014/06/02 A0229 烯丙基醚 Allyl Ether 25ML 568元 2010/06/21 338200250 烯丙基醚 Allyl ether 99% 25 ML 1098元
  • 外观性质:无色液体,有萝卜气味。
  • 下游产品:丁香酚 --> 尼多克罗
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • MSDS 信息:二烯丙基醚(557-40-4).msds
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • 急性毒性:口服- 大鼠 LD50: 320 毫克/ 公斤; 腹腔- 小鼠 LDL0: 250 毫克/ 公斤
  • TCI Shanghai:烯丙基醚 Allyl Ether,>;98.0%(GC)(557-40-4)
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 高热分解刺激气体

系列性分类


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