4-Methylaminophenol hemisulfate, 99%, AR 4-(甲胺基)苯酚半硫酸盐

CAS 55-55-0 MFCD00013140

化学结构图

55-55-0
SMILES: CNC1=CC=C(O)C=C1.OS(O)(=O)=O

化学属性

Mol. FormulaC7H9NO·1/2H2SO4
Mol. Weight172
Autoignition Point989 °F
Melting Point260
TSCAYes
Appearance 无色针状结晶体。熔点259-260℃。溶于20份冷水、6份沸水,微溶于醇,不溶于醚。在空气中变色。
SolubilityH2O: 50 mg/mL, clear
Density1.577
Stability对光线和空气敏感
Boiling Point> 300

别名和识别编码

Chemical Name4-Methylaminophenol hemisulfate, 99%, AR
Synonym 4-(Methylamino)phenol hemisulfate salt
MDL NumberMFCD00013140
CAS Number55-55-0
Beilstein Registry Number3919382
EC Number200-237-1
PubChem Substance ID87572246
Merck Number6017
Reaxys-RN3919382
Chemical Name Translation4-(甲胺基)苯酚半硫酸盐
Wiswesser Line NotationQR DM1 &S-O4
LabNetwork Molecule IDLN01297550
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols, Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy
  • {SNA} Building Blocks, C6 to C8,

产品应用

  • 分离金和钯,还原磷钼酸,检定银,测定金和银。用作感光材料黑白显影剂。

相关文献及参考

  • Merck:14,6017 Beilstein:13,441
  • Merck:14,6017

安全信息

GHS Symbol
RTECSSL8650000
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P362+P364
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P317
  • P319
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P330 Rinse mouth. 漱口
  • P302+P352
  • P333+P317
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
Hazard statements
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Signal word Warning
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Packing GroupIII
UN Number 3077
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36 Irritating to eyes 刺激眼睛
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R48/22
  • R50/53
Storage condition -20°C Air & Light Sensitive 密封阴凉干燥保存。
Hazard Codes 9
Hazard Class9
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KODAK* Kodak Company Reports.  (343 State St., Rochester, NY 14650)
   Volume(issue)/page/year: 21MAY1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 705 mg/kg
TOXIC EFFECTS :
   Behavioral - altered sleep time (including change in righting reflex)
   Behavioral - muscle contraction or spasticity
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 49(9),87,1984

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 565 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - tremor
   Kidney, Ureter, Bladder - other changes in urine composition
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Forme

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 769 mg/kg
TOXIC EFFECTS :
   Behavioral - altered sleep time (including change in righting reflex)
   Behavioral - muscle contraction or spasticity
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 49(9),87,1984

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 167 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 9(Suppl
   9),1,1987

其他信息

  • 上游原料:4-氨基苯酚 --> 对苯
  • color:white to faintly beige
  • 方法一:对氨基苯酚经甲基化或对苯二酚与甲胺反应可制得以甲氨基苯酚([150-75-4]),再经成盐而得。
  • 用途一:用于分离金、钯及还原磷钼酸,也用作显影剂
  • 敏感性:Air Sensitive
  • F:8
  • Sigma Aldrich:55-55-0(sigmaaldrich)
  • 用途三:分离金和钯,还原磷钼酸,检定银,测定金和银。用作感光材料黑白显影剂。该品是具有代表性的主要的快速显影剂。单用或与对苯二酚并用均可,效果都很好,该品的相对还原能力约为对苯二酚的20倍。该品与对苯二酚按1:2-4配比制成的显影液称为MQ显影液;如与偏酸配制,则可用作微粒显影液(胶片敏感度为1、2)。
  • Alfa Aesar:对甲氨基苯酚硫酸盐,99% 4-(Methylamino)phenol sulfate, 99%(55-55-0)
  • 图谱信息:4-甲氨基苯酚硫酸盐(55-55-0)红外图谱(IR1) 4-甲氨基苯酚硫酸盐(55-55-0)红外图谱(IR2) 4-甲氨基苯酚硫酸盐(55-55-0)质谱(MS)
  • TCI Shanghai:4-甲氨基苯酚硫酸盐 4-(Methylamino)phenol Sulfate,>;98.0%(LC)(T)(55-55-0)
  • MSDS 信息:4-Methylaminophenol sulfate(55-55-0).msds
  • Acros Organics:4-甲氨基苯酚硫酸盐 4-Methylaminophenol sulfate, 99%(55-55-0)
  • MOL 文件:55-55-0.mol
  • 用途二:该品是具有代表性的主要的快速显影剂,也常译音为密妥耳。单用或与对苯二酚并用均可,效果都很好,该品的相对还原能力约为对苯二酚的20倍。该品与对苯二酚按1:2-4配比制成的显影液称为MQ显影液;如与偏酸配制,则可用作微粒显影液(胶片敏感度为1/2)。
  • 易溶于水。溶于20份冷水、6份沸水,微溶于醇,不溶于醚。长期接触空气或见光变灰色。
  • 4-甲氨基苯酚硫酸盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30123316 米吐尔 100g 48元 2011/04/16 M0145 4-(甲氨基)苯酚硫酸盐 4-(Methylamino)phenol Sulfate 25G 196元 2011/04/16 M0145 4-(甲氨基)苯酚硫酸盐 4-(Methylamino)phenol Sulfate 500G 1190元

系列性分类


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