5-Norbornene-2-carboxaldehyde, 95%, mixture of endo and exo 5-降冰片烯-2-甲醛

CAS 5453-80-5 MFCD00167568

化学结构图

5453-80-5
SMILES: O=CC1CC2C=CC1C2

化学属性

Mol. FormulaC8H10O
Mol. Weight122
Density1.03
Refractive index1.4860 to 1.4900
Boiling Point67-70
Flash Point50°C(lit.)
TSCAYes
Solubility不溶

别名和识别编码

Chemical Name5-Norbornene-2-carboxaldehyde, 95%, mixture of endo and exo
CAS Number5453-80-5
EC Number226-698-9
Beilstein Registry Number1363813
MDL NumberMFCD00167568
Synonym BICYCLO 2.2.1!HEPT-5-ENE-2- & 5-NORBORNENE-2-CARBALDEHYDE 5-NORBORNENE-2-CARBOXALDEHYDE 5-NORBORNENE-2-CARBOXALDEHYDE, ENDO AND EXO AKOS BC-0598 5-Norbornane-2-carboxaldehyde 5-NORBORNENE-2-CARBOXALDEHYDE, ENDO + EXO, 95% 5-NORBORNENE-2-CARBOXALDEHYDE, 95%, MIXT URE OF ISOMERS 5-降冰片烯-2-甲醛, ENDO + EXO 5-降冰片-2-甲醛 5-Formylbicyclo-2-heptene 5-Formylbicyclohept-2-ene 2-Formyl-5-norbornene BICYCLO[2.2.1]-5-HEPTEN-2-YL METHANAL 双环[2.2.1]庚-5-烯-2-甲醛 5-Formyl-2-norbornene. 5-Norbornene-2-carboxaldehyde,endo+exo,95% Bicyclo[2.2.1]hept-5-en-2-aldehyde 5-Norbornene-2-carboxaldehyde, mixture of endo and exo, 90-95% 5-降冰片烯-2-甲醛 5-norbornene-2-carboxaldehyde,mixtureofendoandexo 5-降冰片烯-2-甲醛,内型结构和外型结构 TIMTEC-BB SBB005755 5-降冰烯-2-甲醛 BICYCLO[2.2.1]HEPT-5-ENE-2-CARBALDEHYDE Bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXALDEHYDE
PubChem Substance ID95117
Reaxys-RN1363813
Chemical Name Translation5-降冰片烯-2-甲醛
InChIKeyAJIBZRIAUXVGQJ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00220733
InChIInChI=1S/C8H10O/c9-5-8-4-6-1-2-7(8)3-6/h1-2,5-8H,3-4H2
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分类

  • {SNA} Aldehydes, Building Blocks, C8, Carbonyl Compounds, Chemical Synthesis, Materials Science, Monomers, Norbornene Monomers, Organic Building Blocks, Polymer Science
  • {SNA} Aldehydes, Building Blocks, C8, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
  • {SNA} Aldehydes, Building Blocks, C8, Carbonyl Compounds, Chemical Synthesis, Monomers, Norbornene Monomers, Organic Building Blocks, Polymer Science, 材料科学

相关文献及参考

  • Aldol condensation with formaldehyde, followed by crossed Cannizzaro reduction, gives norbornene-2,2-dimethanol, from can be thermolyzed to vinyl-1,1-dimethanol: Tetrahedron Lett., 3775 (1975). For a review of cycloreversion reactions in organic synthesis, see: Synthesis, 121 (1985).
  • Diels-Alder adduct of acrolein and cyclopentadiene. Can be used as protected form of acrolein, from which the double bond may be liberated by cycloreversion, e.g. in a useful synthesis of 2-vinylimidazole: Angew. Chem. Int. Ed., 22, 560 (1983):
  • Beilstein: 7,II,125

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P305+P351+P338
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
UN Number 1989
Hazard Codes 3 Xi
Hazard Class3
Storage condition Flammables area

其他信息

  • Acros Organics:5-降冰烯-2-甲醛 5-Norbornene-2-carboxaldehyde, mixture of endo and exo, 90-95%(5453-80-5)
  • Sigma Aldrich:5453-80-5(sigmaaldrich)
  • TCI Shanghai:5-降冰片烯-2-甲醛 5-Norbornene-2-carboxaldehyde,>;95.0%(GC)(5453-80-5)
  • MSDS 信息:5-Norbornene-2-carboxaldehyde(5453-80-5).msds
  • 5-降冰片烯-2-甲醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0504 5-降冰片烯-2-甲醛 5-Norbornene-2-carboxaldehyde 25ML 597元 2010/06/21 149101000 5-降冰片烯-2-甲醛 5-Norbornene-2-carboxaldehyde 90-95%, mixture of endo and exo 100 GR 2361元 2010/06/21 149100250 5-降冰片烯-2-甲醛 5-Norbornene-2-carboxaldehyde 90-95%, mixture of endo and exo 25 GR 937元
  • MOL 文件:5453-80-5.mol
  • Alfa Aesar:5-降冰片烯-2-甲醛,endo+exo,95% 5-Norbornene-2-carboxaldehyde, endo + exo, 95%(5453-80-5)

系列性分类


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