(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 1,2-双[(2R,5R)-2,5-二苯基膦]乙烷(1,5-环辛二烯)四氟硼酸铑(I)
CAS 528565-84-6 MFCD07369037
化学结构图
SMILES: [Rh+].F[B-](F)(F)F.C(CP1[C@H](CC[C@@H]1C1C=CC=CC=1)C1C=CC=CC=1)P1[C@H](CC[C@@H]1C1C=CC=CC=1)C1C=CC=CC=1.C1CC=CCCC=C1
化学属性
| Mol. Formula | C42H48BF4P2Rh |
|---|---|
| Mol. Weight | 804.49 |
| Appearance | orange xtl. |
| Stability | air sensitive |
别名和识别编码
| Chemical Name | (-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate |
|---|---|
| Synonym | 1,2-双[(2R,5R)-2,5-二苯基膦]乙烷(1,5-环辛二烯)四氟硼酸铑(I) (R,R)-Ph-BPE-Rh |
| MDL Number | MFCD07369037 |
| CAS Number | 528565-84-6 |
| Chemical Name Translation | 1,2-双[(2R,5R)-2,5-二苯基膦]乙烷(1,5-环辛二烯)四氟硼酸铑(I) |
| PubChem Substance ID | 329762005 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
