Carboxin 萎锈灵

CAS 5234-68-4 MFCD00055403

化学结构图

5234-68-4
SMILES: CC1=C(C(=O)Nc2ccccc2)SCCO1

化学属性

Mol. FormulaC12H13NO2S
Mol. Weight235.30
Melting Point91.1-91.7°C
Density1.45
Solubility10.095 G/100 ML
Flash Point100°C
Boiling Point420.6±45.0 °C at 760 mmHg

别名和识别编码

Chemical NameCarboxin, 97%, reference material
CAS Number5234-68-4
Alfabeta NameCARBOXIN
MDL NumberMFCD00055403
Synonym Carboxin {LY} Carboxin D 735 D-735 D735 Vitavax {} {LY} Carboxin {} {} {LY} Carboxin {} {} {} {LY} Carboxin {} {} {} {} {LY} Carboxin {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {} {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Carboxin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY}
PubChem Substance ID21307
Beilstein Registry Number983249
EC Number226-031-1
Chemical Name Translation萎锈灵
Merck Number13,1837
Wiswesser Line NotationT6O DS BUTJ B1 CVMR
LabNetwork Molecule IDLN00174662
InChIInChI=1S/C12H13NO2S/c1-9-11(16-8-7-15-9)12(14)13-10-5-3-2-4-6-10/h2-6H,7-8H2,1H3,(H,13,14)
Canonical SMILESO=C(C1=C(C)OCCS1)NC2=CC=CC=C2
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分类

  • Alpha sort, Alphabetic, Amide structure, Analytical Standards, Analytical/Chromatography, C, CA - CG, Chromatography, Environmental Standards, Fungicides, Oxathins, Pesticides, Pesticides & Metabolites
  • {SNA} Amide structure, Analytical Standards, C, Fungicides, Oxathins, 农残和代谢标准品, 农残标准品, 分析/色谱, 按照字母排序
  • {uni_hamburg} no charge; oxygen heterocycle; sulfur heterocycle; carbocycle; aromatic; alicycle; 6RingOnly; 6ring; amide; ether; sulfide; 1fragment
  • {SNA} All Fungicides, Amide structure, Analytical Standards, C,

产品应用

  • 该品为选择性较强的内吸杀菌剂,采用拌种、闷种和浸种等方法防治大小麦、燕麦、玉米、高梁、谷子等禾谷类黑穗病,亦可用于叶面喷酒防治小麦、豆类、梨等锈病,棉花苗期病害及黄萎病、立枯病,也可作木材防腐剂。

相关文献及参考

  • Short: EINECS
  • Short: IV/8A
  • Merck: 14,1827

安全信息

Warnings IRRITANT
RTECSRP4550000
GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Hazard Codes 9
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Signal word Warning
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 430 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - muscle contraction or spasticity
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 23(2),55,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - chicken
DOSE/DURATION           : 24 gm/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   VETNAL Veterinariya.  Veterinary Science.  (V/O Mezhdunarodnaya Kniga,
   113095 Moscow, USSR) V.1-    1924-  Volume(issue)/page/year: 54(6),85,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1050 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zaboleva

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >20 gm/m3/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)  V.1-    1968-  Volume(issue)/page/year:
   9,130,1991

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 382 mg/kg/48H (Continuous)
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   12,235,1988

Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P317
  • P302+P352
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P333+P317
  • P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
UN Number 3077
Packing GroupIII

其他信息

  • MOL 文件:5234-68-4.mol
  • 杀虫剂单一组分标准液
  • 外观性质:米色结晶。
  • 不溶于水,溶于氯仿、丙酮、苯、乙醇等有机溶剂。
  • NIST化学物质信息:Carboxin(5234-68-4)
  • RTECS号:RP4550000
  • EPA化学物质信息:1,4-Oxathiin-3-carboxamide, 5,6-dihydro-2-methyl-N-phenyl- (5234-68-4)
  • 毒害物质数据:5234-68-4(Hazardous Substances Data)
  • 生产方法:由乙酰乙酰苯胺与硫酰氯反应得到α-氯代乙酰乙酰苯胺,再与巯基乙醇缩合而得。原料消耗定额:乙酰乙酰苯胺1090kg/t、硫酰氯880kg/t、巯基乙醇(>95%)490kg/t、对甲苯磺酸30kg/t。
  • 用途:该品为选择性较强的内吸杀菌剂,采用拌种、闷种和浸种等方法防治大小麦、燕麦、玉米、高梁、谷子等禾谷类黑穗病,亦可用于叶面喷酒防治小麦、豆类、梨等锈病,棉花苗期病害及黄萎病、立枯病,也可作木材防腐剂。本品对丝核菌有效,特别适用于棉花、花生、蔬菜和甜菜的种子处理。对作物具有生长刺激作用。萎锈灵对人畜低毒,但不可与眼睛接触。经萎锈灵处理过的种子不可食用或饲用。

系列性分类


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