4-Bromo-1-butene 4-溴-1-丁烯

CAS 5162-44-7 MFCD00000258

化学结构图

5162-44-7
SMILES: C=CCCBr

化学属性

Mol. FormulaC4H7Br
Mol. Weight135.00
Boiling Point99.3°C at 760 mmHg
Density1.33
Refractive index1.4610 to 1.4660
Flash Point1°C
TSCAYes
Stability对光线敏感
Melting Point-115.07 °C

别名和识别编码

Chemical Name4-Bromo-1-butene
CAS Number5162-44-7
Alfabeta NameBROMOBUTENE 41---
MDL NumberMFCD00000258
Synonym Homoallyl bromide {LY} Homoallyl bromide {} {LY} Homoallyl bromide {} {} {LY} Homoallyl bromide {} {} {} {LY} Homoallyl bromide {} {} {} {} {LY} Homoallyl bromide {} {} {} {} {} {LY} Homoallyl bromide {} {} {} {} {} {} {LY} Homoallyl bromide {} {} {} {} {} {} {} {LY} Homoallyl bromide {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} Homoallyl bromide {} {} {} {} {} {} {} {} {} {LY} Homoallyl bromide {} {} {} {} {} {} {} {} {} {} {LY} Homoallyl bromide {} {} {} {} {} {} {} {} {} {} {} {LY} Homoallyl bromide {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Homoallyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Homoallyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Homoallyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Homoallyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number225-937-4
Beilstein Registry Number1098377
PubChem Substance ID21241
Reaxys-RN1098377
Chemical Name Translation4-溴-1-丁烯
InChIKeyDMAYBPBPEUFIHJ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009061
InChIInChI=1S/C4H7Br/c1-2-3-4-5/h2H,1,3-4H2
Canonical SMILESC=CCCBr
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分类

  • Intermediates
  • Aliphatics
  • {uni_hamburg} no charge; 1fragment
  • Miscellaneous Reagents
  • {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

产品应用

  • 4-Bromo-1-butene has been used in a preparation of dienehydrazides which, in turn, provided cyclic enehydrazides by ring closing metathesis. Double alkylation of lactams, followed by Grubbs ring-closing metathesis, gives access to the bicyclic spiroimine ring system of the bicyclic spiroimine ring system of the biotoxin gymnodimine.

相关文献及参考

  • Short: II/25C
  • Beilstein:1(1)84
  • Short: II/14a
  • Short: III/38B

安全信息

Warnings IRRITANT, LACHRYMATOR, FLAMMABLE
Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S24 Avoid contact with skin 避免皮肤接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R42/43
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下,戴呼吸防护。
  • P302+P352
  • P302+P352+P333+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P304+P340+P342+P311
  • P304+P341
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P333+P313
  • P337+P313
  • P342+P311
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number 1993 UN 1993 3/PG 2
Storage condition -20°C {LY} -20°C 2-8°C Light Sensitive {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes 3
Hazard Class3

其他信息

  • MSDS 信息:4-Bromo-1-butene(5162-44-7).msds
  • Acros Organics:4-溴-1-丁烯 4-Bromo-1-butene, 98+%(5162-44-7)
  • 图谱信息:4-溴-1-丁烯(5162-44-7)Raman光谱 4-溴-1-丁烯(5162-44-7)核磁图( 13 CNMR) 4-溴-1-丁烯(5162-44-7)核磁图( 1 HNMR) 4-溴-1-丁烯(5162-44-7)质谱(MS) 4-溴-1-丁烯(5162-44-7)红外图谱(IR1)
  • 灭火剂:雾状水、泡沫、砂土、二氧化碳、1211灭火剂
  • F:8-19
  • 用途一:用作药物中间体
  • 类别:易燃液体
  • 海关编码:29033036
  • Sigma Aldrich:5162-44-7(sigmaaldrich)
  • TCI Shanghai:4-溴-1-丁烯 4-Bromo-1-butene,>;98.0%(GC)(5162-44-7)
  • 4-溴-1-丁烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 S16785101 4-溴-1-丁烯 10g 1642元 2011/04/16 B0920 4-溴-1-丁烯 4-Bromo-1-butene 10G 823元 2011/04/16 B0920 4-溴-1-丁烯 4-Bromo-1-butene 250G 7980元
  • Alfa Aesar:4-溴-1-丁烯,97% 4-Bromo-1-butene, 97%(5162-44-7)
  • MOL 文件:5162-44-7.mol
  • 可燃性危险特性:明火、受热、氧化剂可燃; 遇酸、受热放出含溴化物有毒气体
  • 存储注意事项:光敏感
  • 储运特性:库房通风低温干燥; 轻装轻卸、与氧化剂和酸类分开存放
  • 敏感性:Light Sensitive

系列性分类


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