CAS 5124-30-1 MFCD00015405-Methylene-bis(4-cyclohexylisocyanate) 4,4'-亚甲双(环己基异氰酸酯) TAO{mole}

Methylene-bis(4-cyclohexylisocyanate) 4,4'-亚甲双(环己基异氰酸酯)

CAS 5124-30-1 MFCD00015405

化学结构图

SMILES: O=C=NC1CCC(CC2CCC(N=C=O)CC2)CC1

化学属性

Mol. Formula	C15H22N2O2
Mol. Weight	262
Refractive index	1.4950 to 1.4990
Density	1.066 g/mL at 25 °C(lit.)
Flash Point	>110°(230°F)
TSCA	Yes
Boiling Point	168°C/1.5mmHg(lit.)
Melting Point	26 °C(lit.)
Solubility	不溶/起反应

别名和识别编码

Chemical Name	Methylene-bis(4-cyclohexylisocyanate)
Synonym	1,1'-亚甲二(4-异氰酸基环己烷) 4,4′-HMDI 4,4′-二异氰酸酯二环己基甲烷二环己基甲烷-4,4'-二异氰酸酯 1,1-Methylene bis(4-isocyanatocyclohexane); 1,1'-Methylenebis-(4-Isocyanatocyclohexane); 4,4'-Diisocyanatodicyclohexylmethane; 4,4'-Methylenebis(cyclohexyl isocyanate); Bis(4-isocyanatocyclohexyl) methane; Dicyclohexylmethane-4,4'-diisocyanate; Hydrogenated MDI; Nacconate H 12 1,1’-methylenebis(4-isocyanato-cyclohexan 1,1’-亚甲二(4-异氰酸基环己烷) 4,4&# 4,4'-Dicyclohexylmethane d 4,4'-Methylenebis(cyclohexyl isocyanate) 4,4'-Methylenebis(cyclohexyl isocyanate), mixture of isomers 4,4'-methylenedicyclohexyl diisocyanate 4,4' 4,4'-Diisocyanatodicyclohexylmethane 4,4'-HMDI 4,4'-METHYLENEBIS(CYCLOH 4,4'-Methylenebis(cyclohexyl isocyanate) 4,4'-diisocyanatodicyclohexylmethane 4,4-methylene biscyc
CAS Number	5124-30-1
PubChem Substance ID	21202
EC Number	225-863-2
MDL Number	MFCD00015405
Reaxys-RN	2217800
Beilstein Registry Number	2217800
Chemical Name Translation	4,4'-亚甲双(环己基异氰酸酯)
Wiswesser Line Notation	L6TJ ANCO D1- AL6TJ DNCO
LabNetwork Molecule ID	LN01741806
InChI	InChI=1S/C15H22N2O2/c18-10-16-14-5-1-12(2-6-14)9-13-3-7-15(8-4-13)17-11-19/h12-15H,1-9H2

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安全信息

GHS Symbol

WGK Germany1

Hazard Codes T

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H319 Causes serious eye irritation 严重刺激眼睛
H330 Fatal if inhaled 吸入致命
H331 Toxic if inhaled 吸入中毒
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSNQ9250000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P203
P233 Keep container tightly closed. ?保持容器密闭。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
P301+P330+P331
P302+P350
P302+P352
P302+P352+P333+P313+P362+P364
P302+P361+P354
P303+P361+P353
P304+P340
P304+P340+P310
P304+P340+P312
P304+P341
P305+
P305+P351+P338
P305+P351+P338+P337+P313
P305+P354+P338
P307+P311
P308+P311
P308+P313
P308+P316
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P316
P317
P318
P319
P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P332+P317
P333+P313
P333+P317
P337+P313
P337+P317
P342+P311
P342+P316
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364

Signal word Danger {} {} {} {} {} {} {TCI}

UN Number 2206 UN2206 3080 UN 2206 6.1/PG 2

Storage condition 0-10 0-10°C

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S1/2 None 上锁保管并避免儿童触及；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时，佩带适当的呼吸器；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R42/43
R23 Toxic by inhalation 吸入有毒

Packing GroupII

Hazard Class6.1

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 9900 mg/kg
TOXIC EFFECTS :
   Behavioral - food intake (animal)
   Gastrointestinal - hypermotility, diarrhea
   Liver - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS000555173

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >10 gm/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - food intake (animal)
   Behavioral - muscle weakness
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555173

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 20 ppm/5H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85INA8 "Documentation of the Threshold Limit Values and Biological Exposure
   Indices," 5th ed., Cincinnati, OH, American Conference of Governmental
   Industrial Hygienists, Inc., 1986  Volume(issue)/page/year: 6,998,1991

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 51 mg/m3/1H
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - cyanosis
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   NTIS** National Tec

其他信息

MOL 文件:5124-30-1.mol
4,4-二异氰酸酯二环己基甲烷价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 D2380 二环己基甲烷4,4'-二异氰酸酯(异构体的混和物) Dicyclohexylmethane 4,4'-Diisocyanate (mixture of isomers) 500G 745元 2014/06/02 D2380 二环己基甲烷4,4'-二异氰酸酯(异构体的混和物) Dicyclohexylmethane 4,4'-Diisocyanate (mixture of isomers) 25G 180元 2010/05/25 44087 二环已基甲烷-4,4'-二异氰酸脂, 异构体混合物, 90% Dicyclohexylmethane 4,4'-diisocyanate, mixture of isomers, 90% 50ml 202元
Sigma Aldrich:5124-30-1(sigmaaldrich)
TCI Shanghai:4,4'-二异氰酸酯二环己基甲烷(异构体的混合物) Dicyclohexylmethane 4,4'-Diisocyanate (mixture of isomers),>;90.0%(GC)(5124-30-1)
MSDS 信息:1,1-Methylene bis(4-isocyanatocyclohexane)(5124-30-1).msds
Alfa Aesar:二环已基甲烷-4,4'-二异氰酸脂,异构体混合物,90% Dicyclohexylmethane 4,4'-diisocyanate, mixture of isomers, 90%(5124-30-1)
4,4-二异氰酸酯二环己基甲烷价格(试剂级):更新日期产品编号产品名称包装价格 2011/04/16 D2380 二环己基甲烷4,4'-二异氰酸酯(异构体的混和物) Dicyclohexylmethane 4,4'-Diisocyanate (mixture of isomers) 500G 1030元 2011/04/16 D2380 二环己基甲烷4,4'-二异氰酸酯(异构体的混和物) Dicyclohexylmethane 4,4'-Diisocyanate (mixture of isomers) 25G 208元 2010/05/25 44087 二环已基甲烷-4,4'-二异氰酸脂, 异构体混合物, 90% Dicyclohexylmethane 4,4'-diisocyanate, mixture of isomers, 90% 50ml 202元