N,N,N',N'-Tetramethyldiaminomethane N,N,N′,N′-四甲基甲二胺
CAS 51-80-9 MFCD00008328
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分类
- {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
- Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
- {uni_hamburg} no charge; 1fragment
相关文献及参考
- Caution! The product of double lithiation has been reported to explode on drying: Org. Process Res. Dev., 7, 1029 (2003).
- Has been used as a convenient source of the Mannich intermediate: J. Org. Chem., 33, 1719 (1968). For an example (dimethylaminomethyleneation of ferrocene), see: Org. Synth. Coll., 5, 434 (1973). Reaction with o-hydroxy ɑ-aryl acetophenones leads directly to isoflavanones: Synth. Commun., 29, 3895 (1999):
- Short: II/25D
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P370+P378
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R34 Causes burns 会导致灼伤
- R11 Highly flammable 非常易燃
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S20 When using do not eat or drink 使用时,不得进食,饮水;
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Bird - quail DOSE/DURATION : >316 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : EESADV Ecotoxicology and Environmental Safety. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1977- Volume(issue)/page/year: 6,149,1982
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 220 mg/kg TOXIC EFFECTS : Tumorigenic - active as anti-cancer agent REFERENCE : ARZNAD Arzneimittel-Forschung. Drug Research. (Editio Cantor Verlag, Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.) V.1- 1951- Volume(issue)/page/year: 16,734,1966
其他信息
- 四甲基甲烷二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 T0969 N,N,N',N'-四甲基甲二胺 N,N,N',N'-Tetramethyldiaminomethane 500ML 3700元 2011/04/16 T0969 N,N,N',N'-四甲基甲二胺 N,N,N',N'-Tetramethyldiaminomethane 25ML 446元 2010/06/21 138401000 四甲基甲烷二胺 N,N,N',N'-Tetramethyldiaminomethane 99% 100 ML 1464元
- 下游产品:盐酸氟西汀B
- Sigma Aldrich:51-80-9(sigmaaldrich)
- TCI Shanghai:N,N,N',N'-四甲基甲二胺 N,N,N',N'-Tetramethyldiaminomethane,>;98.0%(GC)(T)(51-80-9)
- Acros Organics:N,N,N',N'-四甲基二氨基甲烷 N,N,N',N'-Tetramethyldiaminomethane, 99%(51-80-9)
- 四甲基甲烷二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0969 N,N,N',N'-四甲基甲二胺 N,N,N',N'-Tetramethyldiaminomethane 500ML 3510元 2014/06/02 T0969 N,N,N',N'-四甲基甲二胺 N,N,N',N'-Tetramethyldiaminomethane 25ML 423元 2010/06/21 138401000 四甲基甲烷二胺 N,N,N',N'-Tetramethyldiaminomethane 99% 100 ML 1464元
- MOL 文件:51-80-9.mol
- 图谱信息:四甲基甲烷二胺(51-80-9)红外图谱(IR2) 四甲基甲烷二胺(51-80-9)核磁图( 1 HNMR) 四甲基甲烷二胺(51-80-9)质谱(MS) 四甲基甲烷二胺(51-80-9)红外图谱(IR1)
- Alfa Aesar:N,N,N',N'-四甲基亚甲二胺,99% N,N,N',N'-Tetramethylmethylenediamine, 99%(51-80-9)