1-Chloro-3-Methyl-2-Butene 氯代异戊烯
CAS 503-60-6 MFCD00000982
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信息真实价格透明
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分类
- {Chemicalbook} 农药中间体: 杀虫剂中间体: 拟除虫菊酯类杀虫剂
- {uni_hamburg} no charge; 1fragment
- {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
相关文献及参考
- Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
- Short: IV/8J Title: Densities of Halohydrocarbons Author: Frenkel, M.; Hong, X.; Dong, Q.; Yan, X.; Chirico, R.D. Editor: Frenkel, M.; Marsh,K.N. Source: Landolt-Börnstein, New Series Volume: IV/8J Year: 2003 Keyword: thermodynamics ISBN: 978-3-540-00083-9 ISBN: 3-540-00083-6 Internet Resource: DOI:10.1007/b10103 RefComment: XII, 600 p., 160 illus., Hardcover RefComment: Written for Scientists and engineers in the fields of physics, chemistry and physical chemistry Abstract: Critically evaluated experimental data covering the densities of organic compounds are essential for both scientific and industrial applications. Knowledge of densities is important in many areas, including custody transfer of materials, product specification, development of various predictive methods, and for characterizing compounds and estimating their purity. This volume contains tables with the original literature data along with their estimated uncertainties and the evaluated data in both numerical form and as coefficients to equations with selected statistical information. When data cover a sufficient temperature range, graphical plots of the deviations of the experimental data from the recommended equation are given. A C
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H319 Causes serious eye irritation 严重刺激眼睛
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P332+P313
- P337+P313
- P302+P352+P332+P313+P362+P364
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P303+P361+P353
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P370+P378
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P403+P235
- P305+P351+P338+P337+P313
- P241+P242+P243
- P233 Keep container tightly closed. ?保持容器密闭。
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R11 Highly flammable 非常易燃
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S33 Take precautionary measures against static discharges 对静电采取预防措施;
- S37 Wear suitable gloves 戴适当手套;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
其他信息
- TCI Shanghai:1-氯-3-甲基-2-丁烯(含稳定剂碳酸钾) 1-Chloro-3-methyl-2-butene (stabilized with K2CO3),>;80.0%(GC)(503-60-6)
- MOL 文件:503-60-6.mol
- MSDS 信息:1-Chloro-3-methyl-2-butene (503-60-6).msds
- 方法一:其制备方法是将异戊二烯与浓盐酸在催化剂CuCl存在下反应,或异戊二烯中通入氯化氢均能得到1-氯-3-甲基丁烯-2和3-氯-3-甲基丁烯-1的混合物,后者经室温下转位可以得到1-氯-3-甲基丁烯-2。反应方程式如图: 在浓盐酸溶液中加入CuCl为催化剂,并进行激烈搅拌使其溶解,然后将温度控制在20℃以下,滴加异戊二烯,滴加完后维持20℃,再继续搅拌0.5h,反应结束,迅速分出有机层,用无水Na 2 CO 3 中和、干燥,常压蒸出未反应的异戊二烯及副反应生成的低沸物,然后减压蒸馏收集79℃/40 kPa馏分即为产品(氯代异戊二烯b.p.105~115℃)。也可用氯化氢通入异戊二烯,反应温度0~10℃,通氯化氢的温度-5℃,用气相色谱控制异戊二烯在反应液中含量以确定反应终点,转位是在室温下搅拌进行4h左右。
- Alfa Aesar:1-氯-3-甲基-2-丁烯,95%,stab.withpotassiumcarbonate 1-Chloro-3-methyl-2-butene, 95%, stab. with potassium carbonate(503-60-6)
- 下游产品:C545T --> 菊酸甲酯 --> 香豆素 314T --> 9-醛基-8-羟基-1,1,7,7-四甲基久洛尼定
- 用途二:氯代异戊烯即1-氯-3-甲基丁烯-2,是Martel法制备菊酸的中间体,也是相模法制备二氯菊酸的中间体。
- 上游原料:浓盐酸 --> 异戊二烯 --> 3-甲基-1-丁烯
- Sigma Aldrich:503-60-6(sigmaaldrich)
- 用途一:用作农药、医药及香料中间体
- 1-氯-3-甲基-2-丁烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1290 1-氯-3-甲基-2-丁烯(含稳定剂碳酸钾) 1-Chloro-3-methyl-2-butene (stabilized with K2CO3) 25ML 539元 2014/06/02 C1290 1-氯-3-甲基-2-丁烯(含稳定剂碳酸钾) 1-Chloro-3-methyl-2-butene (stabilized with K2CO3) 250ML 2300元 2010/05/25 A16545 1-氯-3-甲基-2-丁烯, 95%, stab. with potassium carbonate 1-Chloro-3-methyl-2-butene, 95%, stab. with potassium carbonate 50g 2212元