(S)-SIPHOS-PE (11aS)-(-)-10,11,12,13-四氢茚并[7,1-de:1', 7'-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺

CAS 500997-70-6 MFCD08459342

化学结构图

500997-70-6
SMILES: C[C@@H](C1C=CC=CC=1)N(C(C)C1C=CC=CC=1)P1OC2=CC=CC3CCC4(CCC5C=CC=C(O1)C4=5)C=32 |&1:1|

化学属性

Mol. FormulaC33H32NO2P
Mol. Weight505.59
Melting Point120-125 °C
Density1.422
Appearance white solid
Stabilitymoisture sensitive

别名和识别编码

Chemical Name(S)-SIPHOS-PE
Synonym (11aR)-(+)-10,11,12,13-四氢茚并[7,1-de:1′, 7′-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺 N-二[(R)-1-苯乙基]-[(R)-1,1′-螺二氢茚-7,7′-二基]亚磷酰胺 (11aS)-(-)-10,11,12,13-四氢茚并[7,1-de:1′, 7′-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺 (11aS)-(-)-10,11,12,13-四氢茚并[7,1-de:1′, 7′-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺 N-二[(R)-1-苯乙基]-[(S)-1,1′-螺二氢茚-7,7′-二基]亚磷酰胺 (S)-SIPHOS-PE N-二[(R)-1-苯乙基]-[(S)-1,1′-螺二氢茚-7,7′-二基]亚磷酰胺
MDL NumberMFCD08459342
CAS Number500997-70-6
EC Number250-023-7
Beilstein Registry Number2384789
Chemical Name Translation(11aS)-(-)-10,11,12,13-四氢茚并[7,1-de:1', 7'-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺
PubChem Substance ID329762229
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes Xi

系列性分类


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