2,6-Pyridinedicarboxylic Acid 2,6-二羧酸吡啶

CAS 499-83-2 MFCD00006299

化学结构图

499-83-2
SMILES: O=C(O)C1CCCC(C(=O)O)N1

化学属性

Mol. FormulaC7H5NO4
Mol. Weight167.12
Melting Point248-250°C
TSCAT
Density1.551
Flash Point188°C
Solubility5 G/L (20 ºC)
Appearance 针状结晶。
Boiling Point463.7°C at 760 mmHg

别名和识别编码

Chemical Name2,6-Pyridinedicarboxylic Acid
CAS Number499-83-2
Alfabeta NamePYRIDINEDICARBOXYLICACID 26--,
MDL NumberMFCD00006299
EC Number207-894-3
Beilstein Registry Number22,154
Synonym Pyridine-2,6-dicarboxylic acid {LY} Pyridine-2,6-dicarboxylic acid {} {LY} Pyridine-2,6-dicarboxylic acid {} {} {LY} Pyridine-2,6-dicarboxylic acid {} {} {} {LY} Pyridine-2,6-dicarboxylic acid {} {} {} {} {LY} Pyridine-2,6-dicarboxylic acid {} {} {} {} {} {LY} Pyridine-2,6-dicarboxylic acid {} {} {} {} {} {} {LY} Pyridine-2,6-dicarboxylic acid {} {} {} {} {} {} {} {LY} Pyridine-2,6-dicarboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pyridine-2,6-dicarboxylic acid {} {} {} {} {} {} {} {} {} {LY} Pyridine-2,6-dicarboxylic acid {} {} {} {} {} {} {} {} {} {} {LY} Pyridine-2,6-dicarboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pyridine-2,6-dicarboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pyridine-2,6-dicarboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pyridine-2,6-dicarboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pyridine-2,6-dicarbox
PubChem Substance ID87574730
Chemical Name Translation2,6-二羧酸吡啶
Reaxys-RN131629
LabNetwork Molecule IDLN00121595
InChIInChI=1S/C7H5NO4/c9-6(10)4-2-1-3-5(8-4)7(11)12/h1-3H,(H,9,10)(H,11,12)
Canonical SMILESO=C(C1=NC(C(O)=O)=CC=C1)O
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Electrochemistry, High Purity Reagents for Trace Analysis, Polarography, Reagents for Inorganic Trace Analysis, Trace Analysis Reagents & Solvents
  • {SNA} Electrochemistry,
  • {SA} Building Blocks, C7, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines
  • {SNA} Alphabetical Index of Analytical Standards,
  • {SNA} Analytical Reagents for General Use, Chromatography Reagents & Solvents, Ion Chromatography Reagents, O-P, Puriss p.a., Puriss p.a., Salts and Additives for IC, 分析/色谱, 分析试剂
  • {SNA} Building Blocks, C7, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

产品应用

  • 用于制备二吡啶甲酸连接的镧系元素和过渡金属化合物。

相关文献及参考

  • Beilstein:22,154

安全信息

Warnings IRRITANT
Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36 Irritating to eyes 刺激眼睛
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Gloves
Hazard Codes Xi
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {}

其他信息

  • TCI Shanghai:2,6-吡啶二甲酸 2,6-Pyridinedicarboxylic Acid,>;98.0%(GC)(T)(499-83-2)
  • MOL 文件:499-83-2.mol
  • 图谱信息:吡啶-2,6-二甲酸(499-83-2)红外图谱(IR1) 吡啶-2,6-二甲酸(499-83-2)核磁图( 13 CNMR) 吡啶-2,6-二甲酸(499-83-2)红外图谱(IR2) 吡啶-2,6-二甲酸(499-83-2)核磁图( 1 HNMR) 吡啶-2,6-二甲酸(499-83-2)质谱(MS)
  • Alfa Aesar:吡啶-2,6-二羧酸,98% Pyridine-2,6-dicarboxylic acid, 98%(499-83-2)
  • 用途一:用作牛肝谷氨酸脱氢酶的竞争抑制剂
  • TSCA:T
  • 吡啶-2,6-二甲酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 AP6380801 吡啶-2,6-二甲酸 25g 272元 2011/08/23 K8279001 吡啶-2,6-二羧酸 50g 580元 2011/04/16 P0554 2,6-吡啶二甲酸 2,6-Pyridinedicarboxylic Acid 25G 180元
  • 下游产品:2,6-二乙酰基吡啶 --> 2,6-二氨基-4-氯吡啶 --> (6-甲氧基甲酰氨基-4-氯吡啶-2-基)氨基甲酸甲酯 --> 6-氨基甲基吡啶-2-甲酸 --> 4-氯吡啶-2,6-二碳酰肼 --> 4-氯吡啶-2,6-二羧酸甲酯 --> 6-氨基乙基吡啶-2-碳酰肼 --> 吡啶-2.6-二羧酸二甲酯 --> 6-氯甲基吡啶-3-甲酸乙酯 --> 6-羟甲基吡啶-2-甲酸乙酯 --> 4-氯吡啶-2,6-二羧酸 --> 2,6-吡啶二甲酰氯
  • Hazard Note:Irritant
  • Acros Organics:2,6-吡啶二羧酸 2,6-Pyridinedicarboxylic acid, 99%(499-83-2)
  • MSDS 信息:Dipicolinic acid(499-83-2).msds
  • 海关编码:29333999
  • Sigma Aldrich:499-83-2(sigmaaldrich)
  • 用途二:用于制备二吡啶甲酸连接的镧系元素和过渡金属化合物。
  • 检测方法:HPLC,NMR
  • 上游原料:乙酸乙酯 --> 硫酸 --> 高锰酸钾 --> 2,6-二甲基吡啶
  • 水中溶解度:5 g/l (20°C),溶于沸水,溶于沸乙醇。

系列性分类


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