Chloromethyl chlorosulfate 氯甲基氯磺酸酯

CAS 49715-04-0 MFCD00041547

化学结构图

49715-04-0
SMILES: O=S(=O)(Cl)OCCl

化学属性

Mol. FormulaCH2Cl2O3S
Mol. Weight165
Density1.631
Boiling Point45-50
Refractive index1.4450 to 1.4490
Stability对热和湿度敏感

别名和识别编码

Chemical NameChloromethyl chlorosulfate
MDL NumberMFCD00041547
PubChem Substance ID160871394
CAS Number49715-04-0
EC Number256-442-1
Synonym Chlorosulfonic acid chloromethyl ester 氯甲基氯磺酸酯 氯硫酸氯甲酯
Chemical Name Translation氯甲基氯磺酸酯
LabNetwork Molecule IDLN00225763
Reaxys-RN1703401
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonates/Sulfinates, Sulfur Compounds

产品应用

  • 用于对芴甲氧羰基保护的氨基酸进行氯甲基化的试剂,且不会产生致癌的二氯甲基醚。

相关文献及参考

  • Merck: 14,10386
  • Merck 14 ,10386

安全信息

WGK Germany3
Precautionary statements
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H330 Fatal if inhaled 吸入致命
  • H350 May cause cancer 可能致癌
Hazard Codes C
GHS Symbol
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
Storage condition 0-10°C 储存温度2-8℃
Hazard Class8
UN Number 3265
Packing GroupII

其他信息

  • 和水反应

系列性分类


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