2-Methyl-1,3-Dioxolane 2-甲基-1,3-二茂烷

CAS 497-26-7 MFCD00003210

化学结构图

497-26-7
SMILES: CC1OCCO1

化学属性

Mol. FormulaC4H8O2
Mol. Weight88
Refractive index1.3960 to 1.4000
Boiling Point83°C
Density0.982
Flash Point-2°C(lit.)
TSCAYes
Solubility易溶于水,溶于乙醇、乙醚。

别名和识别编码

Chemical Name2-Methyl-1,3-Dioxolane
Synonym Methyldioxolane 2-甲基-1,3-二氧戊环 2-Methyl-[1,3]dioxolane RARECHEM AL BP 0544 2-METHYL-1,3-DIOXOLANE Acetaldehyde Ethylene Acetal 2-methyl-3-dioxolane 2-METHYL-1,3-DIOXOLANE 98+% 2-Methyldioxole 2-Methyl-1,3-dioxalan Acetaldehyde ethylene acetal 2-methyl-(1,3)dioxolane 2-甲基-1,3-二噁茂烷 2-Methyldioxolane 2-甲基-1,3-二恶茂烷 1,3-Dioxolane, 2-methyl- 2-methoxy-(1,3)dioxolane 2-Methyl-1,3-dioxacyclopentane 2-Methyl-1,3-dioxolane
MDL NumberMFCD00003210
CAS Number497-26-7
PubChem Substance ID87572300
EC Number207-841-4
Beilstein Registry Number19(3/4)42
Reaxys-RN102520
Chemical Name Translation2-甲基-1,3-二茂烷
LabNetwork Molecule IDLN00194481
InChIInChI=1S/C4H8O2/c1-4-5-2-3-6-4/h4H,2-3H2,1H3
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; alicycle; 5ring; 1fragment
  • {SNA} Acetals/Ketals/Ortho Esters, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling consta

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSJI3509000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P305+P351+P338
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P332+P313
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P305+P351+P338+P337+P313
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P241+P242+P243
  • P403+P235
Signal word Danger
Packing GroupII
UN Number UN 1993 3/PG 2 1993
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
  • R11 Highly flammable 非常易燃
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Storage condition Moisture Sensitive Flammables area
Hazard Codes 3
Hazard Class3
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 80 gm/m3
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 39(11),94,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2900 mg/kg
TOXIC EFFECTS :
   Behavioral - excitement
   Behavioral - antipsychotic
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 47(8),89,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3500 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 39(11),94,1974

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 59 gm/m3
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 39(11),94,1974

其他信息

  • Alfa Aesar:2-甲基-1,3-二茂烷,98% 2-Methyl-1,3-dioxolane, 98%(497-26-7)
  • 2-甲基-1,3-二氧戊环价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0210 2-甲基-1,3-二氧戊环 2-Methyl-1,3-dioxolane 25G 637元 2014/06/02 M0210 2-甲基-1,3-二氧戊环 2-Methyl-1,3-dioxolane 500G 5440元 2010/06/21 414200050 2-甲基-1,3-二氧戊环 2-Methyl-1,3-dioxolane 98% 5 GR 354元
  • Acros Organics:2-甲基-1,3-二氧戊环 2-Methyl-1,3-dioxolane, 98%(497-26-7)
  • 图谱信息:2-甲基-1,3-二氧戊环(497-26-7)红外图谱(IR1) 2-甲基-1,3-二氧戊环(497-26-7)质谱(MS) 2-甲基-1,3-二氧戊环(497-26-7)核磁图( 13 CNMR)
  • Sigma Aldrich:497-26-7(sigmaaldrich)
  • MOL 文件:497-26-7.mol
  • MSDS 信息:2-甲基-1,3-二氧戊环(497-26-7).msds
  • 外观性质:无色液体。
  • 敏感性:Moisture Sensitive
  • TCI Shanghai:2-甲基-1,3-二氧戊环 2-Methyl-1,3-dioxolane,>;98.0%(GC)(497-26-7)

系列性分类


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