2,2'-Bithiophene 联二噻吩

CAS 492-97-7 MFCD00005414

化学结构图

492-97-7
SMILES: c1csc(-c2cccs2)c1

化学属性

Mol. FormulaC8H6S2
Mol. Weight166.26
Boiling Point260°C at 760 mmHg
Melting Point32-33°C
TSCAT
Density1.243
Flash Point110°C
Stability对光敏感

别名和识别编码

Chemical Name2,2’-Bithiophene
CAS Number492-97-7
Alfabeta NameBITHIOPHENE 22-,'
MDL NumberMFCD00005414
Synonym 2-(2-Thienyl)thiophen {LY} 2-(2-Thienyl)thiophen {} {LY} 2-(2-Thienyl)thiophen {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {} {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {} {} {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {} {} {} {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {} {} {} {} {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(2-Thienyl)thiophen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number207-767-2
Beilstein Registry Number19(3/4)265
PubChem Substance ID68120
Chemical Name Translation联二噻吩
Reaxys-RN3039
InChIKeyOHZAHWOAMVVGEL-UHFFFAOYSA-N
LabNetwork Molecule IDLN00116964
Canonical SMILESC1(C2=CC=CS2)=CC=CS1
InChIInChI=1S/C8H6S2/c1-3-7(9-5-1)8-4-2-6-10-8/h1-6H
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分类

  • {uni_hamburg} no charge; sulfur heterocycle; aromatic; 5ring; sulfide; 1fragment
  • {SNA} Building Blocks, C7 to C9, Chemical Synthesis, Heterocyclic Building Blocks, Materials Science, Organic and Printed Electronics, Synthetic Tools and Reagents, Thiophene Monomers and Building Blocks, Thiophenes
  • {SNA} Building Blocks, C7 to C9, Chemical Synthesis, Heterocyclic Building Blocks, Thiophenes
  • {SNA} Building Blocks, C7 to C9, Chemical Synthesis, Heterocyclic Building Blocks, Organic and Printed Electronics, Synthetic Tools and Reagents, Thiophene Monomers and Building Blocks, Thiophenes, 材料科学

相关文献及参考

  • Short: II/25D
  • Short: III/5a
  • Can be converted to its 5-lithio- and 5,5'-dilithio derivatives by PhLi and n-BuLi respectively. Chemistry of this type has found applications in synthesis of: liquid crystal molecules: Mol. Cryst. Liq. Cryst. Sci. Technol. Sect. A, 218, 113 (1992); bithienoquinoid compounds as electron donors for organic conductors: Tetrahedron Lett., 33, 5405 (1992); conjugated thiophene oligomers as organic semiconductors: J. Am. Chem. Soc., 115, 8716 (1993); polythiophenes as conducting polymers: Synth. Met., 55, 420 (1993).
  • Beilstein:19(3/4)265
  • {

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P317
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P317
  • P337+P317
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Light Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from l
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves
Hazard Codes Xi
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

  • 图谱信息:联二噻吩(492-97-7)质谱(MS)
  • Acros Organics:联噻吩 2,2'-Bithiophene, 97%(492-97-7)
  • TSCA:T
  • 下游产品:2,2'-联噻吩-5-硼酸 --> 2,2-联噻吩-5-乙醛
  • TCI Shanghai:2,2'-联噻吩 2,2'-Bithiophene,>;98.0%(GC)(492-97-7)
  • F:10-23
  • Hazard Note:Irritant
  • Sigma Aldrich:492-97-7(sigmaaldrich)
  • MOL 文件:492-97-7.mol
  • 联二噻吩价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1276 2,2'-联噻吩 2,2'-Bithiophene 1G 98元 2014/06/02 B1276 2,2'-联噻吩 2,2'-Bithiophene 10G 560元 2014/06/02 B1276 2,2'-联噻吩 2,2'-Bithiophene 25G 870元
  • Alfa Aesar:2,2'-二噻吩,98% 2,2'-Bithiophene, 98%(492-97-7)

系列性分类