(Methoxymethyl)diphenylphosphine oxide (甲氧基甲基)二苯基磷氧
CAS 4455-77-0 MFCD00015451
化学结构图
SMILES: COCP(=O)(c1ccccc1)c1ccccc1
化学属性
| Mol. Formula | C14H15O2P |
|---|---|
| Mol. Weight | 246.24 |
| Melting Point | 113-120 °C |
| TSCA | No |
| Boiling Point | 334.7±25.0 °C at 760 mmHg |
别名和识别编码
| Chemical Name | [(methoxymethyl)(phenyl)phosphoroso]benzene |
|---|---|
| MDL Number | MFCD00015451 |
| CAS Number | 4455-77-0 |
| Synonym | (Methoxymethyl)diphenylphosphine oxide {LY} (Methoxymethyl)diphenylphosphine oxide {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Me |
| PubChem Substance ID | 78203 |
| Beilstein Registry Number | 649558 |
| EC Number | 224-704-4 |
| Chemical Name Translation | (甲氧基甲基)二苯基磷氧 |
| Reaxys-RN | 649558 |
| InChIKey | OEPKDBQOTLDTNC-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00222937 |
| InChI | InChI=1S/C14H15O2P/c1-16-12-17(15,13-8-4-2-5-9-13)14-10-6-3-7-11-14/h2-11H,12H2,1H3 |
| Canonical SMILES | COCP(C1=CC=CC=C1)(C2=CC=CC=C2)=O |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
相关文献及参考
- Horner olefination with aldehydes and ketones gives vinyl ethers (and hence higher aldehydes). The method is reported to be superior to the Wittig alternative. The two diastereoisomeric adducts can also be isolated and each converted to a single stereoisomer of the enol ether: J. Chem. Soc., Perkin 1, 3099 (1979):
安全信息
GHS Symbol
- H302 Harmful if swallowed 吞食有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R22 Harmful if swallowed 吞咽有害
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P301+P312
- P301+P312+P330
- P301+P317
- P330 Rinse mouth. 漱口
- P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 1500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
KHFZAN Khimiko-Farmatsevticheskii Zhurnal. Chemical Pharmaceutical Journal.
For English translation, see PCJOAU. (V/O Mezhdunarodnaya Kniga, 113095
Moscow, USSR) V.1- 1967- Volume(issue)/page/year: 24(4),22,1990