4,5-Dimethoxy-2-Nitrobenzyl Carbonochloridate 4,5-二甲氧基-2-硝基苄基氯甲酸酯
CAS 42855-00-5 MFCD00143507
化学结构图
SMILES: COC1=CC(COC(=O)Cl)=C(C=C1OC)[N+]([O-])=O
化学属性
| Mol. Formula | C10H10ClNO6 |
|---|---|
| Mol. Weight | 276 |
| Melting Point | 120-125° |
| TSCA | No |
别名和识别编码
| Chemical Name | 4,5-Dimethoxy-2-Nitrobenzyl Carbonochloridate |
|---|---|
| CAS Number | 42855-00-5 |
| Alfabeta Name | DIMETHOXYNITROBENZYLCARBONOCHLORIDATE 452---, |
| MDL Number | MFCD00143507 |
| Synonym | NVOC-Cl Chloroformic acid 6-nitroveratryl ester 6-硝基藜芦基氯甲酸酯 NVOC 氯化物 4,5-二甲氧基-2-硝基苄基氯甲酸酯 6-硝基藜芦氯甲酸 6-硝基藜芦基氯甲酸酯 6-硝基藜芦氯甲酸 NVOC 氯化物 NVOC-Cl |
| Beilstein Registry Number | 2389168 |
| PubChem Substance ID | 24866307 |
| Chemical Name Translation | 4,5-二甲氧基-2-硝基苄基氯甲酸酯 |
| InChIKey | RWWPKIOWBQFXEE-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00135712 |
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分类
- {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
- Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry,
相关文献及参考
- FT-IR 2 (2), 2960:D / Structure Index 1 , 318:A:7
- Reagent for protection of amines. The group is readily cleaved photolytically: Tetrahedron Lett., 29, 65 (1988). For use in N-protection of bases in nucleotide synthesis, see: J. Org. Chem., 64, 6319 (1999). For reviews of photochemical protecting groups in organic synthesis, see: Synthesis, 1 (1980); Org. Photochem., 9, 225 (1987).
安全信息
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R37 Irritating to respiratory system 刺激呼吸道
- R34 Causes burns 会导致灼伤
