Trifluoro(Trifluoromethyl)Oxirane 六氟环氧丙烷
CAS 428-59-1 MFCD00005125
化学结构图
SMILES: FC(F)(F)C1(F)OC1(F)F
化学属性
| Mol. Formula | C3F6O |
|---|---|
| Mol. Weight | 166.02 |
| Boiling Point | -28 ºC |
| Melting Point | -129 ºC |
| Appearance | 白色结晶体，熔点 -129℃ ，沸点 -28℃ |
别名和识别编码
| Chemical Name | Trifluoro(Trifluoromethyl)Oxirane |
|---|---|
| Synonym | 2,2,3-Trifluoro-3-(trifluoromethyl)oxirane {LY} 2,2,3-Trifluoro-3-(trifluoromethyl)oxirane 2-(Trifluoromethyl)-2,3,3-trifluorooxirane 2-(Trifluoromethyl)trifluorooxirane 2-Trifluoromethyl-2,3,3-trifluorooxirane HEXAFLUORO-1,2-EPOXYPROPANE HEXAFLUOROEPOXYPROPANE HEXAFLUOROPROPENE OXIDE HEXAFLUOROPROPYLENE OXIDE HFPO Hexa Hexafluoro-1,2-epoxypropane Hexafluoro-1,2-epoxypropane; 1,2-Epoxy-1,1,2,3,3,3-hexafluoropropane; Trifluoro(trifluoromethyl)oxirane Hexafluoroepoxypropane Hexafluoropropene epoxide Hexafluoropropene oxide Hexafluoropropene-1,2-oxide {} {LY} 2,2,3-Trifluoro-3-(trifluoromethyl)oxirane {} {} {LY} 2,2,3-Trifluoro-3-(trifluoromethyl)oxirane {} {} {} {LY} 2,2,3-Trifluoro-3-(trifluoromethyl)oxirane {} {} {} {} {LY} 2,2,3-Trifluoro-3-(trifluor |
| MDL Number | MFCD00005125 |
| PubChem Substance ID | 9883 |
| CAS Number | 428-59-1 |
| EC Number | 207-050-4 |
| Chemical Name Translation | 六氟环氧丙烷 |
| LabNetwork Molecule ID | LN01995731 |
| InChI | InChI=1S/C3F6O/c4-1(2(5,6)7)3(8,9)10-1 |
| Canonical SMILES | FC(C1(F)C(F)(F)O1)(F)F |
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分类
- Chemical Synthesis, Electronic Chemicals, Fluorine-Containing Monomers for 157 nm UV Lithography Resist Polymers, Gases, Lithography Monomers, Materials Science, Micro/NanoElectronics, Self Assembly & Contact Printing, Specialty Gases, Synthetic Reagents
- {uni_hamburg} no charge; oxygen heterocycle; alicycle; 3ring; racemate; 1fragment
- {SNA} Chemical Synthesis, Electronic Chemicals, Fluorine-Containing Monomers for 157 nm UV Lithography Resist Polymers, Gases, Lithography Monomers, Materials Science, Micro/NanoElectronics, Self Assembly & Contact Printing, Specialty Gases, Synthetic Reagents
相关文献及参考
- Beil. 17 ,IV,20
- RegBook 1 (1), 249:A / Structure Index 1 , 33:C:9
- Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
安全信息
GHS Symbol
- P410+P403
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H280 Contains gas under pressure; may explode if heated 内含高压气体，遇热可能爆炸。
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S7 Keep container tightly closed 保存在严格密闭容器中；
- S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时，佩带适当的呼吸器；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R44 Risk of explosion if heated under confinement 密封下加热有爆炸危险
其他信息
- MOL 文件:428-59-1.mol
- 下游产品:六氟丙酮
- Hazard Note:Irritant
- Sigma Aldrich:428-59-1(sigmaaldrich)
- MSDS 信息:Hexafluoropropylene oxide(428-59-1).msds
- 用途一:作为一个重要的含氟中间体，主要用于合成高档的含氟功能化合物
