Trimethylfluorosilane 氟代三甲基硅烷
CAS 420-56-4 MFCD00042064
化学结构图
SMILES: C[Si](C)(C)F
化学属性
| Mol. Formula | C3H9FSi |
|---|---|
| Mol. Weight | 92.19 |
| Density | 0.793 g/mL at 25 °C(lit.) |
| Boiling Point | 16 °C(lit.) |
| Melting Point | -74 °C(lit.) |
| Flash Point | -30 ºC |
别名和识别编码
| Chemical Name | Trimethylfluorosilane |
|---|---|
| Synonym | (CH3)3SiF FLUOROTRIMETHYLSILANE Fluorotrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
| MDL Number | MFCD00042064 |
| CAS Number | 420-56-4 |
| Beilstein Registry Number | 1731132 |
| EC Number | 206-997-0 |
| PubChem Substance ID | 24862438 |
| Chemical Name Translation | 氟代三甲基硅烷 |
| InChIKey | CTIKAHQFRQTTAY-UHFFFAOYSA-N |
| Canonical SMILES | C[Si](C)(F)C |
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分类
- {uni_hamburg} no charge; 1fragment
- {SNA} Chemical Synthesis, Specialty Gases, Synthetic Reagents
相关文献及参考
- Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
- Short: II/4 Title: Molecular Constants from Microwave Spectroscopy Author: Starck, B. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/4 Page: 1-225 Year: 1967 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-03896-5 ISBN: 978-3-540-03896-2 Internet Resource: DOI:10.1007/b19949 RefComment: 67 figs., X
- Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.;
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
- H319 Causes serious eye irritation 严重刺激眼睛
- H280 Contains gas under pressure; may explode if heated 内含高压气体，遇热可能爆炸。
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P410+P403
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R12 Extremely flammable 极端易燃
其他信息
- F:4.5-9-21
- Sigma Aldrich:420-56-4(sigmaaldrich)
- Hazard Note:Flammable
- MOL 文件:420-56-4.mol
- TSCA:Yes
