Tris(2-Aminoethyl)Amine 三(2-氨基乙基)胺
CAS 4097-89-6 MFCD00008177
化学结构图
SMILES: NCCN(CCN)CCN
化学属性
| Mol. Formula | C6H18N4 |
|---|---|
| Mol. Weight | 146.23 |
| Density | 0.976 |
| Refractive index | 1.4950 to 1.4990 |
| Vapor Density | 5 (vs air) |
| Boiling Point | 114 °C at 15 mmHg |
| Vapor Pressure | 0.02 mmHg ( 20 °C) |
| Flash Point | >110°(230°F) |
| TSCA | Yes |
| Melting Point | -16 °C |
| Appearance | saline suspension |
| Stability | 对空气敏感，易吸湿 |
别名和识别编码
| Chemical Name | Tris(2-Aminoethyl)Amine |
|---|---|
| Synonym | N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {} |
| CAS Number | 4097-89-6 |
| EC Number | 223-857-4 |
| Beilstein Registry Number | 4(2)695 |
| MDL Number | MFCD00008177 |
| PubChem Substance ID | 77731 |
| Chemical Name Translation | 三(2-氨基乙基)胺 |
| Reaxys-RN | 1739626 |
| InChIKey | MBYLVOKEDDQJDY-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00199022 |
| InChI | InChI=1S/C6H18N4/c7-1-4-10(5-2-8)6-3-9/h1-9H2 |
| Canonical SMILES | NCCN(CCN)CCN |
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分类
- {SNA} Amine Monomers, Materials Science, Monomers, Polymer Science, Primary Amines
- {SA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
- {uni_hamburg} no charge; 1fragment
- {SNA} Amine Monomers, Monomers, Polymer Science, Primary Amines, 材料科学
产品应用
- 可作为穴状配体的结构单元和有机非离子超强碱的前体。
相关文献及参考
- Beilstein:4(2)695
- Reagent for rapid cleavage of the Fmoc group in peptide synthesis, particularly recommended in conjunction with Fmoc-protected acid chlorides as the active species: J. Org. Chem., 55, 1673 (1990). For a review of peptide synthesis via amino ac
- Short: III/35B
- Short: IV/20C
- Short: EINECS
- Reagent for rapid cleavage of the Fmoc group in peptide synthesis, particularly recommended in conjunction with Fmoc-protected acid chlorides as the active species: J. Org. Chem., 55, 1673 (1990). For a review of peptide synthesis via amino acid halides, see: Acc. Chem. Res., 29, 268 (1996). For peptide reagents, see Appendix 6.
- Reaction with aryl isocyanates and isothiocyanates gives tris-urea and -thiourea derivatives which have been evaluated as phosphate and sulfate receptors: Chem. Lett., 759 (1995).
安全信息
GHS Symbol
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
- R24 Toxic in contact with skin 与皮肤接触有毒
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R10 Flammable 易燃
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P301+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P302+P350
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338+P310
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P330+P331+P310
- P303+P361+P353
- P304+P340
- H301 Toxic if swallowed 吞食有毒
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H310 Fatal in contact with skin 皮肤接触致命
其他信息
- 三(2-氨基乙基)胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1243 三(2-氨乙基)胺 Tris(2-aminoethyl)amine 25ML 524元 2011/04/16 T1243 三(2-氨乙基)胺 Tris(2-aminoethyl)amine 500ML 9199元 2010/06/21 314791000 三(2-氨基乙基)胺 Tris(2-aminoethyl)amine 96% 100 ML 1637元
- TCI Shanghai:三(2-氨乙基)胺 Tris(2-aminoethyl)amine,>;98.0%(T)(4097-89-6)
- Alfa Aesar:三（2-氨乙基）胺,97% Tris(2-aminoethyl)amine, 97%(4097-89-6)
- MOL 文件:4097-89-6.mol
- Sigma Aldrich:4097-89-6(sigmaaldrich)
- 敏感性:Hygroscopic
- 蒸气压:0.02 mm Hg ( 20 °C)
- 蒸气密度:5 (vs air)
- 上游原料:氢氧化钠 --> 盐酸 --> 甲醇 --> 氢氧化铵 --> 次氯酸钠 --> 1,2-二氯乙烷 --> 丙烯酰胺 --> 直接红 28
- Acros Organics:三（2-氨乙基）胺 Tris(2-aminoethyl)amine, 96%(4097-89-6)
- F:3-10-23
