(1R,2R)-N,N’-Bis(2-Acetyl-3-Oxo-2-Butenylidene)-1,2-Dimesitylethylenediaminato Cobalt(Ii) (1R,2R)-N,N’-双(2-乙酰-3-氧代-2-亚丁烯基)-1,2-二均三甲苯基乙二胺合钴
CAS 361346-80-7 MFCD06797061
化学结构图
SMILES: CC(=O)C1C=N[C@@H]([C@H](N=CC(=C(C)O[Co]OC=1C)C(C)=O)C1C(C)=CC(C)=CC=1C)C1C(C)=CC(C)=CC=1C |c:24,27,34,37,t:4,8,10,16,29,39|
化学属性
| Mol. Formula | C32H38CoN2O4 |
|---|---|
| Mol. Weight | 573.60 |
| Melting Point | 246-250 °C |
别名和识别编码
| Chemical Name | (1R,2R)-N,N’-Bis(2-Acetyl-3-Oxo-2-Butenylidene)-1,2-Dimesitylethylenediaminato Cobalt(Ii) |
|---|---|
| MDL Number | MFCD06797061 |
| CAS Number | 361346-80-7 |
| Synonym | (R,R)-AMAC (1R,2R)-N,N′-双(2-乙酰-3-氧代-2-亚丁烯基)-1,2-二均三甲苯基乙二胺合钴(II) |
| PubChem Substance ID | 87565147 |
| Chemical Name Translation | (1R,2R)-N,N’-双(2-乙酰-3-氧代-2-亚丁烯基)-1,2-二均三甲苯基乙二胺合钴 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Reduction
安全信息
GHS Symbol
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P308+P313
- P332+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P301+P312+P330
- P302+P350
- P337+P313
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P304+P340+P312
- P305+P351+P338+P337+P313
- P405 Store locked up. 上锁保管。
- P302+P352+P312+P362+P364
- H302+H312+H332
- H332 Harmful if inhaled 吸入有害
- H315 Causes skin irritation 会刺激皮肤
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H319 Causes serious eye irritation 严重刺激眼睛
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S22 Do not breathe dust 不要吸入粉尘；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
