Tris[N,N-bis(trimethylsilyl)amide]europium(III) 三[N,N-双(三甲基硅烷)胺]铕(III)

CAS 35789-02-7 MFCD03411248

化学结构图

35789-02-7
SMILES: C[Si](C)(C)N([Eu](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

化学属性

Mol. FormulaEu(N(Si(CH3)3)2)3
Mol. Weight633.12
Melting Point147-154 °C(lit.)
TSCANo
Boiling Point105°10|-^4mm

别名和识别编码

Chemical NameTris[N,N-bis(trimethylsilyl)amide]europium(III)
Synonym 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine europium salt Europium(III) tris[N,N-bis(trimethylsilyl)amide] 三[N,N-双(三甲基硅烷)胺]铕(III)
CAS Number35789-02-7
PubChem Substance ID24878982
MDL NumberMFCD03411248
Chemical Name Translation三[N,N-双(三甲基硅烷)胺]铕(III)
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分类

  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Europium, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors
  • {SA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Europium, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors
  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Europium, Micro/NanoElectronics, Vapor Deposition Precursors, 材料科学

相关文献及参考

  • 1. P. L. Arnold, et al., Angew. Chem. Int. Ed. Engl. 47 , 6033-6036, (2008)
  • 2. H. C. Aspinall, et al., Organometallics 19 , 5416-5423, (2000)
  • 3. T. J. Boyle, et al., Inorg. Chem. 46 , 3705-3713, (2007)
  • 4. M. A. Katkova, et al., Inorg. Chim. Acta 359 , 4289-4296, (2006)

安全信息

GHS Symbol
WGK Germany3
Hazard Codes F,C
Hazard statements
  • H228 Flammable solid 易燃固体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
UN Number UN3396
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R34 Causes burns 会导致灼伤
Storage condition Moisture Sensitive
Packing GroupII

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Europium - Catalysis and Inorganic Chemistry
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors Packaged for Deposition Systems - Vapor Deposition Precursors
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Europium - CVD and ALD Precursors by Metal
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rare-Earth Metals 稀土金属化合物

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