(2-(Tert-Butoxy)-2-Oxoethyl)Triphenylphosphonium Chloride (2-(叔丁氧基)-2-氧代乙基)三苯基鏻氯化物
CAS 35000-37-4 MFCD00043160
化学结构图
SMILES: [Cl-].CC(C)(C)OC(=O)C[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | (CH3)3CO2CCH2P(C6H5)3Cl |
|---|---|
| Mol. Weight | 413 |
| Melting Point | ca 190° dec. |
| TSCA | No |
别名和识别编码
| Chemical Name | (2-(Tert-Butoxy)-2-Oxoethyl)Triphenylphosphonium Chloride |
|---|---|
| Beilstein Registry Number | 4116684 |
| PubChem Substance ID | 24852241 |
| CAS Number | 35000-37-4 |
| MDL Number | MFCD00043160 |
| Synonym | Carbo-tert-butoxymethyl triphenylphosphonium chloride (叔丁氧基羰基甲基)氯化三苯基磷 |
| Chemical Name Translation | (2-(叔丁氧基)-2-氧代乙基)三苯基鏻氯化物 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- 1. Mahboobi, S.; et al. J. Med. Chem. 53 , 8546, (2010)
- 2. Castaneda, F.; et al. Phosph. Sulfur Relat. Elem. 183 , 1188, (2008)
- 3. B.B. Snider et al. J. Am. Chem. Soc. 101 , 6023, (1978)
- 4. M.P. Cooke et al. J. Org. Chem. 47 , 4955, (1982)
- 5. M. Regitz et al. Liebigs Ann. Chem. , 1865, (1981)
安全信息
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
