2,5-Dibromothiophene 2,5-二溴噻吩

CAS 3141-27-3 MFCD00005420

化学结构图

3141-27-3
SMILES: Brc1ccc(Br)s1

化学属性

Mol. FormulaC4H2Br2S
Mol. Weight241.93
Boiling Point209.5°C at 760 mmHg
Melting Point-6°C
TSCAT
Refractive index1.6280 to 1.6300
Density2.147
Flash Point99°C
Solubility难溶
Stability对光敏感
Appearance 淡黄色透明液体,沸点211℃,熔点-6℃,相对密度2.147。

别名和识别编码

Chemical Name2,5-Dibromothiophene
CAS Number3141-27-3
Alfabeta NameDIBROMOTHIOPHENE 25-,
MDL NumberMFCD00005420
Synonym 2,5-Dibromothiophene {LY} 2,5-Dibromothiophene {} {LY} 2,5-Dibromothiophene {} {} {LY} 2,5-Dibromothiophene {} {} {} {LY} 2,5-Dibromothiophene {} {} {} {} {LY} 2,5-Dibromothiophene {} {} {} {} {} {LY} 2,5-Dibromothiophene {} {} {} {} {} {} {LY} 2,5-Dibromothiophene {} {} {} {} {} {} {} {LY} 2,5-Dibromothiophene {} {} {} {} {} {} {} {} {LY} 2,5-Dibromothiophene {} {} {} {} {} {} {} {} {} {LY} 2,5-Dibromothiophene {} {} {} {} {} {} {} {} {} {} {LY} 2,5-Dibromothiophene {} {} {} {} {} {} {} {} {} {} {} {LY} 2,5-Dibromothiophene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,5-Dibromothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,5-Dibromothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,5-Dibromothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,5-Dibromothiophene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID18453
EC Number221-547-3
Reaxys-RN109899
Beilstein Registry Number605953
Chemical Name Translation2,5-二溴噻吩
LabNetwork Molecule IDLN00117190
InChIInChI=1S/C4H2Br2S/c5-3-1-2-4(6)7-3/h1-2H
Canonical SMILESBrC1=CC=C(Br)S1
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分类

  • Building Blocks, C4 to C6, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Thiophenes
  • {uni_hamburg} no charge; sulfur heterocycle; aromatic; 5ring; 1fragment
  • {SNA} Building Blocks, C4 to C6, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Thiophenes

相关文献及参考

  • For selective Mg exchange at the 2-position, see: J. Org. Chem., 65, 4618 (2000).
  • Beilstein:17(5)1,308
  • Short: III/20b
  • Short: III/38B

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes T+,Xi T+ Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H300 Fatal if swallowed 吞食致命
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P305+P351+P338
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
UN Number UN2810 2810
Risk Statements
  • R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
  • R28 Very toxic if swallowed 吞咽极毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupII
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class6.1

其他信息

  • MOL 文件:3141-27-3.mol
  • 2,5-二溴噻吩价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1549 2,5-二溴噻吩 2,5-Dibromothiophene 25G 535元 2010/06/21 148680250 2,5-二溴噻吩 2,5-Dibromothiophene 95% 25 GR 494元 2010/06/21 148681000 2,5-二溴噻吩 2,5-Dibromothiophene 95% 100 GR 1346元
  • 下游产品:5-溴噻吩-2-甲酰肼 --> 邻氨基噻吩(2盐酸) --> 5-溴噻吩-2-甲酸乙酯 --> 5,5'-二溴-2,2'-联噻吩 --> 5-溴硫代苯-2-甲酸乙酯 --> alpha-三联噻吩
  • MSDS 信息:2,5-Dibromothiophene(3141-27-3).msds
  • TSCA:T
  • 不溶于水。
  • Acros Organics:2,5-二溴噻吩 2,5-Dibromothiophene, 95%(3141-27-3)
  • Alfa Aesar:2,5-二溴噻吩,96% 2,5-Dibromothiophene, 96%(3141-27-3)
  • Hazard Note:Irritant
  • 检测方法:GC,NMR
  • Sigma Aldrich:3141-27-3(sigmaaldrich)
  • 存储注意事项:光敏感
  • TCI Shanghai:2,5-二溴噻吩 2,5-Dibromothiophene,>;95.0%(GC)(3141-27-3)
  • 图谱信息:2,5-二溴噻吩(3141-27-3)核磁图( 13 CNMR) 2,5-二溴噻吩(3141-27-3)红外图谱(IR1) 2,5-二溴噻吩(3141-27-3)质谱(MS) 2,5-二溴噻吩(3141-27-3)核磁图( 1 HNMR)

系列性分类