N,N,N’,N’’,N’’-Pentamethyldiethylenetriamine 五甲基二乙烯三胺

CAS 3030-47-5 MFCD00014876

化学结构图

3030-47-5
SMILES: CN(C)CCN(C)CCN(C)C

化学属性

Mol. FormulaC9H23N3
Mol. Weight173.30
Refractive index1.4410 to 1.4430
Boiling Point198 °C at 760 mmHg
Density0.830
Melting Point-20 °C
Flash Point72°C(lit.)
TSCAYes
Autoignition Point311 °F
Vapor Pressure0.23 mmHg ( 20 °C)
Stability对空气敏感
Appearance 五甲基二乙烯三胺(3030-47-5)为无色至浅黄色透明液体，能溶于水、醚及醇类溶剂，能吸收空气中的水分及二氧化碳。相对密度(d420):0.9132-0.9442，折光率(nD20):1.4430-1.4450，沸点 85-86℃，熔点 18-20℃

别名和识别编码

Chemical NameN,N,N’,N’’,N’’-Pentamethyldiethylenetriamine
Synonym N1-(2-(Dimethylamino)ethyl)-N1,N2,N2-trimethylethane-1,2-diamine {LY} N1-(2-(Dimethylamino)ethyl)-N1,N2,N2-trimethylethane-1,2-diamine {} {LY} N1-(2-(Dimethylamino)ethyl)-N1,N2,N2-trimethylethane-1,2-diamine {} {} {LY} N1-(2-(Dimethylamino)ethyl)-N1,N2,N2-trimethylethane-1,2-diamine {} {} {} { {} {} {} {LY} N1-(2-(Dimethylamino)ethyl)-N1,N2,N2-trimethylethane-1,2-diamine {} {} {} {} {LY} N1-(2-(Dimethylamino)ethyl)-N1,N2,N2-trimethylethane-1,2-diamine {} {} {} {} {} {LY} N1-(2-(Dimethylamino)ethyl)-N1,N2,N2-trimethylethane-1,2-diamine {} {} {} {} {} {} {LY} N1-(2-(Dimethylamino)ethyl)-N1,N2,N2-trimethylethane-1,2-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1-(2-(Dimethylamino)ethyl)-N1,N2,N2-trimethylethane-1,2-diamine {} {} {} {} {} {} {} {} {LY} N1-(2-(Dimethylamino)ethyl)-N1,N2,N2-trimethylethane-1,2-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1-(2-(Dimethylamino)ethyl)-N1,N2,N2-trimethylethane-1,2-diamine
CAS Number3030-47-5
PubChem Substance ID18196
EC Number221-201-1
Beilstein Registry Number1741396
MDL NumberMFCD00014876
Reaxys-RN1741396
Chemical Name Translation五甲基二乙烯三胺
Wiswesser Line Notation1N1&2N1&2N1&1
LabNetwork Molecule IDLN00222324
InChIInChI=1S/C9H23N3/c1-10(2)6-8-12(5)9-7-11(3)4/h6-9H2,1-5H3
Canonical SMILESCN(C)CCN(CCN(C)C)C
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分类

  • {SNA} ATRP, ATRP Ligands, Amine Monomers, Monomers, Polymer Science, Reagents for Controlled Radical Polymerization, Reagents for Polymerization, Tertiary Amines, 材料科学
  • {SNA} ATRP, ATRP Ligands, Amine Monomers, Materials Science, Monomers, Polymer Science, Reagents for Controlled Radical Polymerization, Reagents for Polymerization, Tertiary Amines

产品应用

  • 用NMR研究新戊基锂络合作用的配体，以及研究和α,ω-二炔相互作用的CO2的配体效果。N,N,N',N'',N''-五甲基二乙烯三胺催化剂是一种高活性的叔胺催化剂，由于它独有的氨基氮的空间屏蔽交应，其碱性的特质能更有效的对水和异氰酸酯之间的反应起催化作用，因此N,N,N',N'',N''-五甲基二乙烯三胺一种极佳的硬质泡沫和软质泡沫的发泡催化剂，故常与DMCHA等共用。N,N,N',N'',N''-五甲基二乙烯三胺亦用于平衡整体发泡及凝胶反应。

相关文献及参考

  • Beilstein: 4,IV,1240

安全信息

GHS Symbol
WGK Germany2
Hazard Codes 8 T
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H227 Combustible liquid 可燃液体
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSIE2100000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P303+P361+
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2734 2922
Risk Statements
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupII
Storage condition 2-8°C {LY} 2-8°C Air & Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°
Hazard Class8/6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 280 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1630 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

其他信息

  • 凝固点:<-70℃
  • MOL 文件:3030-47-5.mol
  • TCI Shanghai:N,N,N',N'',N''-五甲基二乙三胺 N,N,N',N'',N''-Pentamethyldiethylenetriamine,>;98.0%(GC)(3030-47-5)
  • 用途一:用作聚氨基甲酸酯软泡的高效催化剂
  • F:10-34
  • 敏感性:Air Sensitive
  • Alfa Aesar:1，1，4，7，7-五甲基二乙烯基三胺,98% 1,1,4,7,7-Pentamethyldiethylenetriamine, 98%(3030-47-5)
  • 下游产品:1-苯基-5-三氟甲基-1H-吡唑-4-醛 --> 1-苯基-5-三氟甲基-4-溴-1H-吡唑 --> 2,5-二氯异烟酸
  • 是一种高活性的叔胺催化剂，独有的氨基氮的空间屏蔽交应，其碱性的特质能更有效的对水和异氰酸酯之间的反应起催化作用。
  • Sigma Aldrich:3030-47-5(sigmaaldrich)
  • Acros Organics:N N N' N' N''-五甲基二乙烯三胺 1,1,4,7,7-Pentamethyldiethylenetriamine, 99+%(3030-47-5)
  • 蒸气压:0.23 mm Hg ( 20 °C)
  • 海关编码:29212900
  • 用途二:用NMR研究新戊基锂络合作用的配体，以及研究和α,ω-二炔相互作用的CO2的配体效果。N,N,N',N'',N''-五甲基二乙烯三胺催化剂是一种高活性的叔胺催化剂，由于它独有的氨基氮的空间屏蔽交应，其碱性的特质能更有效的对水和异氰酸酯之间的反应起催化作用，因此N,N,N',N'',N''-五甲基二乙烯三胺一种极佳的硬质泡沫和软质泡沫的发泡催化剂，故常与DMCHA等共用。N,N,N',N'',N''-五甲基二乙烯三胺亦用于平衡整体发泡及凝胶反应。
  • 检测方法:GC,NMR
  • MSDS 信息:PMDTA(3030-47-5).msds
  • 五甲基二乙烯三胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0881 N,N,N',N'',N''-五甲基二亚乙基三胺 N,N,N',N'',N''-Pentamethyldiethylenetriamine 25ML 168元 2014/06/02 P0881 N,N,N',N'',N''-五甲基二亚乙基三胺 N,N,N',N'',N''-Pentamethyldiethylenetriamine 500ML 832元 2010/06/21 416955000 五甲基二乙烯三胺 1,1,4,7,7-Pentamethyldiethylenetriamine 99+% 500 GR 7669元
  • 图谱信息:五甲基二乙烯三胺(3030-47-5)质谱(MS) 五甲基二乙烯三胺(3030-47-5)核磁图( 13 CNMR) 五甲基二乙烯三胺(3030-47-5)红外图谱(IR1) 五甲基二乙烯三胺(3030-47-5)核磁图( 1 HNMR)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Polyamines - Nitrogen Compounds
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Amine Monomers - Monomers
  5. Tertiary Amines - Amine Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Oximes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Amine Monomers
  5. Secondary Amines

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