CAS 302-15-8 MFCD00035423-Methylhydrazine sulfate 甲基肼硫酸盐 TAO{mole}

Methylhydrazine sulfate 甲基肼硫酸盐

CAS 302-15-8 MFCD00035423

化学结构图

SMILES: CNN.O=S(=O)(O)O

化学属性

Mol. Formula	CH8N2O4S
Mol. Weight	144.15
Melting Point	143°C
TSCA	Yes
Appearance	甲基肼硫酸盐(302-15-8)为甲基肼的硫酸盐。甲基肼为澄明液体，沸点 87.5℃，呈强还原性，与强氧化剂接触易燃烧，闪点 70℃，对皮肤及黏膜有强刺激性，并显示很强的生理毒性；甲基肼硫酸盐为白色片状结晶，熔点 141-142℃，使用比较安全。

别名和识别编码

Chemical Name	Methylhydrazine sulfate
CAS Number	302-15-8
Synonym	Methylhydrazine sulfate {LY} Methylhydrazine sulfate {} {LY} Methylhydrazine sulfate {} {} {LY} Methylhydrazine sulfate {} {} {} {LY} Methylhydrazine sulfate {} {} {} {} {LY} Methylhydrazine sulfate {} {} {} {} {} {LY} Methylhydrazine sulfate {} {} {} {} {} {} {LY} Methylhydrazine sulfate {} {} {} {} {} {} {} {LY} Methylhydrazine sulfate {} {} {} {} {} {} {} {} {LY} Methylhydrazine sulfate {} {} {} {} {} {} {} {} {} {LY} Methylhydrazine sulfate {} {} {} {} {} {} {} {} {} {} {LY} Methylhydrazine sulfate {} {} {} {} {} {} {} {} {} {} {} {LY} Methylhydrazine sulfate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methylhydrazine sulfate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methylhydrazine sulfate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methylhydrazine sulfate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methylhydrazine sulfate {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL Number	MFCD00035423
EC Number	206-115-4
Merck Number	14,6086
Beilstein Registry Number	3693575
Reaxys-RN	3693575
PubChem Substance ID	165286
Chemical Name Translation	甲基肼硫酸盐
Wiswesser Line Notation	ZM1 &WSQQ
LabNetwork Molecule ID	LN00221312
InChI	InChI=1S/CH6N2.H2O4S/c1-3-2;1-5(2,3)4/h3H,2H2,1H3;(H2,1,2,3,4)
Canonical SMILES	O=S(O)(O)=O.CNN

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产品应用

A substituted hydrazine used in the preparation of pyrazole-3-carboxamide derivatives as 5-HT2B receptor antagonists.

安全信息

RTECSMV7750000

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；

Packing GroupIII

UN Number 2811

Risk Statements

R000923/24/25
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用

Signal word

Hazard statements

H301+H311+H331

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310+P330
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P403+P233
P302+P352+P312+P361+P364
P501 Dispose of contents/container to..… 处理内容物/容器.....
P405 Store locked up. 上锁保管。
P304+P340+P311
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P302+P350
P301+P310
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
P302+P352
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。

Hazard Class6.1

GHS Symbol

Hazard Codes

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2092 mg/kg/83W-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   IJCNAW International Journal of Cancer.  (International Union Against
   Cancer, 3 rue du Conseil- General, 1205 Geneva, Switzerland)  V.1-    1966-
   Volume(issue)/page/year: 9,109,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 160 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RPTOAN Russian Pharmacology and Toxicology (English Translation).
   Translation of FATOAO.  (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey,
   UK)  V.30-    1967-  Volume(issue)/page/year: 36,27,1973

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Rodent - mouse Liver
DOSE/DURATION           : 100 umol/L
REFERENCE :
   JJCREP Japanese Journal of Cancer Research. (Elsevier Science Pub. BV, POB
   211, 1000 AE Amsterdam, Netherlands)  V.76-    1985-
   Volume(issue)/page/year: 79,204,1988

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 10 umol/L
REFERENCE :
   JJCREP Japanese Journal of Cancer Research. (Elsevier Science Pub. BV, POB
   211, 1000 AE Amsterdam, Netherlands)  V.76-    1985-
   Volume(issue)/page/year: 79,204,1988

Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Store at room temperature {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro

其他信息

方法一:用肼与苯甲醛缩合，生成苄叉连氮，后都与硫酸二甲酯在苯中回流反应得到该品。
上游原料:苄连氮
MOL 文件:302-15-8.mol
Sigma Aldrich:302-15-8(sigmaaldrich)
Alfa Aesar:甲基硫酸肼,98% Methylhydrazine sulfate, 98%(302-15-8)
甲基肼硫酸盐价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 M0341 硫酸甲肼 Methylhydrazine Sulfate 25G 1120元 2010/05/25 L10122 甲基硫酸肼, 98% Methylhydrazine sulfate, 98% 5g 493元 2010/05/25 L10122 甲基硫酸肼, 98% Methylhydrazine sulfate, 98% 25g 1764元
下游产品:甲基肼 --> 5-氨基-1,3-二甲基吡唑 --> (6R,7R)-7-[[(2E)-2-(2-氨基-1,3-噻唑-4-基)-2-甲氧基亚氨乙酰]氨基]-3-[(2-甲基-5,6-二氧代-1H-1,2,4-三嗪-3-基)硫甲基]-8-氧代-5-硫-1-氮杂双环[4.2.0]辛-2-烯-2-甲酸 --> 4-氯-1,3-二甲基-1H-吡唑3,4-吡啶-5-羧酸 --> 二甲基异唑四异氰酸酯 --> 1-甲基-5-三氟甲基-4-溴-1H-吡唑 --> 4-氯-1,3-二甲基吡唑并[3,4-B]吡啶-5-羰酰氯 --> 1,3-二甲基-4-氯-1H-吡唑[3,4-B]并吡啶-5-甲酸乙酯
用途一:甲基苄肼（异丙胺酰苄肼）的中间体。甲基肼为火箭燃料。
TCI Shanghai:硫酸甲肼 Methylhydrazine Sulfate,>;98.0%(T)(302-15-8)
图谱信息:甲基肼硫酸盐(302-15-8)红外图谱(IR1) 甲基肼硫酸盐(302-15-8)核磁图( 1 HNMR) 甲基肼硫酸盐(302-15-8)核磁图( 13 CNMR)
MSDS 信息:Methylhydrazine sulfate (302-15-8).msds