1,1-Bis(tert-butylperoxy)cyclohexane 1,1-双(叔丁基过氧基)环己烷

CAS 3006-86-8 MFCD00084800

化学结构图

3006-86-8
SMILES: CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1

化学属性

Mol. FormulaC6H10[OOC(CH3)3]2
Mol. Weight260.37
Refractive indexn20/D 1.435
Density0.891 g/mL at 25 °C
Melting Point65 °C (SADT)
Boiling Point52-54 ºC (0.1 MMHG)
SolubilityMISCIBLE
Flash Point155 °F

别名和识别编码

Chemical Name1,1-Di(Tert-Butylperoxy)Cyclohexane
Synonym 1,1-Bis(tert-butylperoxy)cyclohexane; Cyclohexylidenebis(tert-butyl)peroxide; Trigonox 22; Luperox 331M80 1,1-BIS(T-BUPEROXY)CYCLOHEXANE, 80 WT. % 1,1-二(叔丁基过氧)环己烷 溶液 AC-1#固化剂 1,1-二(叔丁过氧化)环己烷 1,1-二叔丁基过氧化环己烷 1 1-BIS(T-BUTYLPEROXY)CYCLOHEXANE TECH& Luperox® 331M80, 1,1-双（叔丁基）环己烷 溶液 Trigonox 22 Dibutyl peroxycyclohexanone paste cyclohexylidenebis(tert-butyl)peroxide Peroxide,cyclohexylidenebis[(1,1-dimethylethyl) 1,1-DI(TERT-BUTYLPEROXY)CYCLOHEXANE DP275B 引发剂DP275B Cyclohexylidenebis[(1,1-dimethylethyl)peroxide] 1,1-双(叔丁基过氧基)环己烷 LUPEROX(TM) 331M80 1,1-Bis(tert-butylperoxy)cyclohexane solution 1,1-Bis(tert-butylperoxy)cyclohexane (Luperox(R) 331M80) solution 1,1-BIS(TERT-BUTYLPEROXY)CYCLOHEXANE 1,1-双(叔丁基)过氧环己烷 TRIGONOX(R) 22 Initiating agent DP275B 50%solutioninmineraloil 引发剂A Luperox 331M80 1,1-Di(tert-butylperoxy)cyclohexane, 50% solution in mineral oil 1,1-双（叔丁基）环己烷; 1,1-二叔丁基过氧化环己烷 1,1-Di-(tert.-butylperoxy)-cyclohexan 过氧化环己酮二丁酯糊 1,1-bis(T-butylperoxy)cyclohexane
CAS Number3006-86-8
PubChem Substance ID76359
MDL NumberMFCD00084800
EC Number221-111-2
Beilstein Registry Number2384789
Chemical Name Translation1,1-双(叔丁基过氧基)环己烷
LabNetwork Molecule IDLN03251325
InChIInChI=1S/C14H28O4/c1-12(2,3)15-17-14(10-8-7-9-11-14)18-16-13(4,5)6/h7-11H2,1-6H3
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分类

  • {SNA} Free Radical Initiators, Organic Peroxides, Polymer Science, Polymerization Initiators, Reagents for Polymerization, 材料科学
  • {SNA} Free Radical Initiators, Materials Science, Organic Peroxides, Polymer Science, Polymerization Initiators, Reagents for Polymerization
  • Free Radical Initiators, Materials Science, Organic Peroxides, Polymer Science, Polymerization Initiators

产品应用

  • 聚合引发剂.

相关文献及参考

  • FT-IR 2 (1), 306:A / Structure Index 1 , 29:A:5

安全信息

GHS Symbol
WGK Germany3
Hazard Codes O O,T O,N,T
Hazard statements
  • H242 Heating may cause a fire 加热可能会引起火灾
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H340 May cause genetic defects 可能导致遗传性缺陷
  • H350 May cause cancer 可能致癌
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P235 Keep cool. 保持凉爽。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P316
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P370+P380+P375
  • P378 Use … for extinction. 使用...灭火。
  • P403 Store in a well-ventilated place. 储存在通风良好的地方。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P410 Protect from sunlight. 防止阳光照射。
  • P411 Store at temperatures not exceeding … oC/…oF. 储存在温度不超过…oC /…oF。
  • P420 Store away from other materials. 远离其他材料。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S14 Keep away from ... (incompatible materials to be indicated by the manufacturer) 远离（生产厂家指定的不相容物质）保存；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S17 Keep away from combustible material 远离可燃物料；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R46 May cause inheritable genetic damage 可能引起遗传基因损害
  • R45 May cause cancer 可能致癌
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R7 May cause fire 会导致起火
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R50/53
UN Number UN 3103 5.2 3103
Packing GroupII
Hazard Class5.2
Storage condition Refrigerator (+4°C) 储存温度2-8℃
Warnings 危化品目录(2015) 危险化学品

其他信息

  • MOL 文件:3006-86-8.mol
  • 用途一:用作聚苯乙烯、低压聚乙烯的引发剂，不饱和聚酯、硅橡胶的交联剂
  • 用途二:用作玻璃钢制品的固化剂
  • Sigma Aldrich:3006-86-8(sigmaaldrich)
  • Acros Organics:1,1-Di(tert-butylperoxy)cyclohexane, 50% solution in aromatic free mineral spirit(3006-86-8)
  • 1,1-二叔丁基过氧化环己烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 361312500 1,1-二叔丁基过氧化环己烷 1,1-Di(tert-butylperoxy)cyclohexane , 50% solution in mineral oil 250 ML 890元 2010/06/21 361310100 1,1-二叔丁基过氧化环己烷 1,1-Di(tert-butylperoxy)cyclohexane , 50% solution in mineral oil 10 ML 241元
  • MSDS 信息:Trigonox 22(3006-86-8).msds

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. I - Alphabetic
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Arenes 芳烃
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymerization Initiators - Polymer Science
  4. Free Radical Initiators and Materials for Controlled Radical Polymerization
  5. Organic Peroxides - Free Radical Initiators
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Polymerization Initiators
  4. Free Radical Initiators
  5. Inorganic Peroxides

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