CAS 29169-64-0 MFCD00799229-(R)-O-Formylmandeloyl Chloride (R)-(-)-O-甲酰基扁桃酸酰氯 TAO{mole}

(R)-O-Formylmandeloyl Chloride (R)-(-)-O-甲酰基扁桃酸酰氯

CAS 29169-64-0 MFCD00799229

化学结构图

SMILES: O=C(Cl)[C@H](OC=O)c1ccccc1

化学属性

Mol. Formula	C9H7ClO3
Mol. Weight	198.60
Refractive index	1.5200 to 1.5240
Boiling Point	221
Density	1.275
Flash Point	>;230 °F
Appearance	亚氨基芪(256-96-2)为黄色或橙色结晶性粉末，熔点198.0-202.0°c，溶于酸，碱，甲苯，DMF及吡啶，微溶于醇。 powder
Solubility	dioxane: 50 mg/mL, clear
Melting Point	197 °C

别名和识别编码

Chemical Name	(R)-O-Formylmandeloyl Chloride
Synonym	IMINOSTILBENE (NON-BROMINE FREE) 亚氨基二苯乙烯 (R)-(-)-α-(甲酰氧基)苯乙酰氯亚氨基联芪 5H-Dibenz[b,f]azepin 亚氨基芪 2,3,6,7-Dibenzazepine R(-)-ALPHA-(FORMYLOXY)PHENYLACETYLCHLORIDE Iminostilben D(-)ALPHA-FORMYLOXY-ALPHA-PHENYLACETYLCHLORIDE (-)-O-甲酰-D-扁桃酰氯 (R)-(-)-α-(甲酰氧基)苯乙酰氯 (-)-O-FORMYL-D-MANDELOYL CHLORIDE CARBAMAZEPINE INTERMEDIATES (R)-(-)-α-(甲酰氧基)苯乙酰氯 Stilbene, 2,2'-imino- (R)-(-)-O-FORMYLMANDELOYL CHLORIDE (-)-O-甲酰-D-扁桃酰氯 FORMYLOXYMANDELOYL CHLORIDE Iminostibene carbonyl chloride (R)-(-)-O-甲酰基扁桃酸酰氯 R-FMOC 5H-Dibenzo(b,f)azepine 5H-Dibenz[b,f]azepine (-)-O-甲酰-D-扁桃酰氯 (R)-(-)-α-(甲酰氧基)苯乙酰氯 5H-二苯并[B,F]氮杂 Iminostilbene D-(-)-O-FORMYL MANDELOYL CHLORIDE 军二苯代乙烯亚胺亚胺基 IMINOSTILBENE (BROMINE FREE) (R)-O-FORMYL-MANDELOYL CHLORIDE 亚氨基联芪 (无溴、无荧光) 5-Azadibenzo(a,e)cycloheptatriene Dibenz(b,f)azepine
CAS Number	29169-64-0
PubChem Substance ID	87561438
EC Number	249-478-4
Beilstein Registry Number	5404068
MDL Number	MFCD00799229
Reaxys-RN	5404068
Chemical Name Translation	(R)-(-)-O-甲酰基扁桃酸酰氯
InChIKey	ZNLABNPTWSKGDX-UHFFFAOYSA-N

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H290 May be corrosive to metals 可能腐蚀金属。
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 8 C C,Xi,N,Xn

Precautionary statements

P234 Keep only in original container. 只保留在原来的容器中。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331
P301+P330+P331+P310
P303+P361+P353+P310+P363
P304+P340
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
P405 Store locked up. 上锁保管。
P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

UN Number 3265

Packing GroupII

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

R34 Causes burns 会导致灼伤

Hazard Class8

其他信息

图谱信息:亚氨基芪(256-96-2)红外图谱(IR1) 亚氨基芪(256-96-2)红外图谱(IR2) 亚氨基芪(256-96-2)质谱(MS) 亚氨基芪(256-96-2)核磁图( 13 CNMR) 亚氨基芪(256-96-2)核磁图( 1 HNMR)
用途一:用作医药中间体，用于合成药品卡马西平等
亚氨基芪价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 I0414 亚氨基芪 Iminostilbene 25G 1020元 2010/06/21 162541000 亚氨基芪 Iminostilbene 97% 100 GR 6734元 2010/06/21 162540100 亚氨基芪 Iminostilbene 97% 10 GR 1168元
上游原料:氮杂 --> 二苯
方法一:由10.11二氢-5H-二苯骈[b,f]氮杂[494-19-9]经消除而得。
MOL 文件:256-96-2.mol
Sigma Aldrich:256-96-2(sigmaaldrich)
Acros Organics:亚氨基芪 Iminostilbene, 97%(256-96-2)
Hazard Note:Irritant
color:yellow to orange
F:10-21
TCI Shanghai:亚氨基芪 Iminostilbene,>;98.0%(GC)(N)(256-96-2)
下游产品:亚氨基芪甲酰氯 --> 卡马西平 --> 酰氯亚氨基二苄
MSDS 信息:5H-Dibenz[b,f]azepine(256-96-2).msds
Alfa Aesar:亚氨基芪,97% Iminostilbene, 97%(256-96-2)
用途二:医药中间体，用于生产镇痛抗痉挛药痛惊宁。